Humidity‐based power generation that converts internal energy of water molecules into electricity is an emerging approach for harvesting clean energy from nature. Here it is proposed that intrinsic gradient within a humidity field near sweating surfaces, such as rivers, soil, or animal skin, is a promising power resource when integrated with liquid‐infused nanofluidics. Specifically, capillary‐stabilized ionic liquid (IL, Omim+Cl‐) film is exposed to the above humidity field to create a sustained transmembrane water‐content difference, which enables asymmetric ion‐diffusion across the nanoconfined fluidics, facilitating long‐term electricity generation with the power density of ≈12.11 µW cm‐2. This high record is attributed to the nanoconfined IL that integrates van der Waals and electrostatic interactions to block movement of Omim+ clusters while allowing for directional diffusion of moisture‐liberated Cl+. This humidity gradient triggers large ion‐diffusion flux for power generation indicates great potential of sweating surfaces considering that most of the earth is covered by water or soil.
Influence of strain-induced indium clustering on characteristics of InGaN/GaN multiple quantum wells with high indium compositionGreen-light-emission InGaN / GaN multiple quantum wells ͑MQWs͒ with different polarities were grown by metal organic chemical vapor deposition. A clear phase separation was observed both in the Ga-and N-polarity samples by high resolution transmission electron microscopy, corresponding to two InGaN-related emissions ͑In-rich dots and an InGaN matrix͒ seen in photoluminescence spectra. The dot-related emission in the Ga-polarity MQWs shows stronger carrier localization, as well as a weak influence of defects and temperature insensitivity, when compared to the N-polarity MQWs. In addition, efficient carrier transport, from the low-indium InGaN matrix to high-indium In-rich dots, was observed in the Ga-polarity structure, enhancing the function of quantum-dot structures with Ga polarity, and resulting in a high quantum yield of green light emission.
Temperature and time evolution of the photoluminescence ͑PL͒ intensity of bimodal ZnTe/ ZnSe type-II quantum dots ͑QDs͒ were investigated. A particular temperature dependence of PL was observed in large QDs. PL decay of small QDs is composed of a faster initial component and a slower tail component whereas PL decay of large QDs simply comprises a fast component. All phenomena could be understood consistently by considering charge carrier transfer mechanism, band-bending effect, and the existence of nonradiative centers in the bimodal type-II QD array. We show that excitons play an important role in the emission properties of a self-assembled type-II QD system.
ZnO films were grown on (0001) sapphire substrates by atomic layer deposition (ALD) using diethylzinc (DEZn) and nitrous oxide (N 2 O) in an inductively heated reactor operated at atmospheric pressure. Low-temperature (LT) ZnO buffer layers having various thicknesses were deposited at 400 followed by subsequent growth of ZnO films at 600 . Some of the ZnO films were then post-annealed at 1000 in the N 2 O flow. Under certain growth conditions, ZnO nanowires were formed on the post-annealed ZnO samples. Room temperature (RT) photoluminescence (PL) spectra of the ZnO nanowires show strong ultraviolet (UV) near band edge emissions at 3.27 eV with a typical full width at half-maximum ( FWHM ) of ~130 meV and quenched defect luminescence. 10 K PL spectra of the post-annealed ZnO all exhibit sharp excitonic emissions with the dominant emission being located at 3.36 eV having a FWHM of 4.6 meV.
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