The quality of soils polluted by trace elements around the facilities with the Cu and Zn smelting activities and the post-flotation tailings pond from copper industry were assessed. The level of the contamination of soils was determined on the basis of the contamination factor and the geoaccumulation index. The geoaccumulation index allows to distinguish more degrees of soil contamination and simplifies the assessment of the useable value of soil. The degrees of soil contamination and the pollution load index were shown. It has been shown that the pollution indices are a useful tool in describing the soil quality and planning corrective actions in the areas contaminated as a result of industrial activity. Histograms of pollution indices were used in order to detect the distribution of trace elements in soils. The content of metals in biomass was assessed using bioaccumulation indices. Triticum L. and Brassica napus L. show low bioaccumulation of studied metals in cereal plants. The correlations were used in order to detect the relationship among trace elements in soil as well as the relationship of metal (soil)-metal (plant) and metal bioaccumulation (plant)-metal (soil). The highest values of indices were recorded for the Oława smelter, presumably due to the long operation period before technological changes limiting the emission of pollutants were introduced. This research area was classified as very highly contaminated with all trace elements. Soils around other facilities are at least moderately contaminated.

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Copper and zinc concentrations in soils and grasses near selected communication routes in Wrocław, Poland have been determined. Environmental samples were collected from the surface layer of the soil profile within 3 m from the edge of the road. The analysis of metals in the mineralizates has been carried out by atomic absorptive spectroscopy (AAS). The conductivity and pH of the soil solutions were measured to evaluate the salinity of the soils and also their active and exchangeable acidity. There have been determined the parameters characterizing the content of metals in soils and grasses, the index of the enrichment of soils in zinc and copper (Wn), the bioaccumulation coefficient (WB), histograms of the frequency of metals occurrence in environmental samples. Also it was presented the Pearson's r correlation coefficients for the relationships: Zn in soil/Cu in soil, Zn in grass/Cu in grass, Cu in grass/Cu in soil, Zn in grass/Zn in soil. The research does not indicate exceeding of the permissible content of copper and zinc in the environment. However, in all samples higher content of the metals compared to the geochemical background have been observed.