Intermediate depth disposal operations were conducted by the U.S. Department of Energy (DOE) at the DOE's Nevada Test Site (NTS) from 1984 through 1989. These operations emplaced highspecific activity low-level wastes (LLW) and limited quantities of classified, "special case" transuranic (TRU) wastes in 37 m (120-ft) deep, 3 m (10 ft) diameter Greater Confinement Disposal (GCD) boreholes.Four boreholes contain about 60,000 kg (132,000 lb.) of classified TRU waste packages, containing less than 330 curies of Plutonium-239. All of the TRU wastes emplaced in the GCD boreholes are classified for national security reasons and cannot be disposed of in the DOE's Waste Isolation Pilot Plant.The U.S. Environmental Protection Agency's (EPA's) 40 CFR 191 defines the requirements for protection of human health from disposed TRU wastes. This EPA standard sets a number of requirements, including probabilistic limits on the cumulative releases of radionuclides to the accessible environment for 10,000 years. This report presents the performance assessment (PA) that has been conducted to determine if disposal of TRU waste in the GCD boreholes complies with the EPA's 40 CFR 191 requirements.Sandia National Laboratories completed this PA using all available information and an Iterative PA Methodology, which focused work on uncertainty reduction in a cost-effective fashion that does not overestimate system performance and assured defensibility. The simplicity of the conceptual models of the GCD disposal system allowed them to be implemented in Microsoft ® Visual Basic™ macros in an Access™ database. This PA model is built from a mathematical expression for mass conservation that includes the operation of a number of transport processes, including dissolution, precipitation, reversible chemical sorption onto soil, advection, diffusion, dispersion, radioactive decay and ingrowth, plant uptake, and bioturbation. The mathematical model and implementing code was used to calculate a complementary cumulative distribution function of integrated normalized release to the accessible environment for 10,000 years and probability distributions of dose based on two exposure conditions for the 1,000 year individual protection requirements.The primary conclusions of this PA are that the disposal of TRU wastes in the GCD boreholes will, at most, result in minuscule doses to individuals, and that the GCD disposal system easily meets the EPA's 1985, 40 CFR 191 requirements for disposal of TRU waste. Further, there is a strong, reasonable expectation that actual system performance will be better than what is simulated in this PA.vi ACKNOWLEDGMENTS
Sandia National Laboratories has completed thermal performance testing on the Schott parabolic trough receiver using the LS-2 collector on the Sandia rotating platform at the National Solar Thermal Test Facility in Albuquerque, NM. This testing was funded as part of the US DOE Sun-Lab USA-Trough program. The receiver tested was a new Schott receiver, known as Heat Collector Elements (HCEs). Schott is a new manufacturer of trough HCEs. The Schott HCEs are 4m long; therefore, two were joined and mounted on the LS-2 collector module for the test. The Schott HCE design consists of a 70mm diameter high solar absorptance coated stainless steel (SS) tube encapsulated within a 125mm diameter Pyrex ® glass tube with vacuum in the annulus formed between the SS and glass tube to minimize convection heat losses. The Schott HCE design is unique in two regards. First, the bellows used to compensate for the difference in thermal expansion between the metal and glass tube are inside the glass envelope rather than outside. Second, the composition of materials at the glass-to-metal seal has very similar thermal expansion coefficients making the joint less prone to breakage from thermal shock. Sandia National Laboratories provided both the azimuth and elevation collector module tracking systems used during the tests. The test results showed the efficiency of the Schott HCE to be very similar to current HCEs being manufactured by Solel. This testing provided performance verification for the use of Schott tubes with Solargenix trough collector assemblies at currently planned trough power plant projects in Arizona and Nevada.
The present generation of commercial parabolic trough solar power plant uses a synthetic oil as the heat transport fluid in the collector field. The plants are currently operating at the upper temperature limit of the fluid, and further improvements in the solar-to-electric conversion efficiency are likely to be incremental. In contrast, adoption of a nitrate salt, or a nitrate/nitrite salt, mixture as the heat transport fluid would allow the collector field outlet temperature to increase by 50 to 100 °C, which translates into an increase in the gross Rankine cycle efficiency from the present 37.5 percent to new values in the range of 40 to 41 percent. Further, the low cost and the low vapor pressure of the candidate salt mixtures allow the heat transport fluid to also act as the storage medium in a thermal storage system. Using a salt mixture in the collector field should reduce the unit cost of thermal storage by approximately half compared to the current indirect designs. The principal, and far from minor, liability of the candidate salt mixtures are freezing points in the range of 120 °C to 220 °C. As a consequence, all salt components, including the collector field, will require some form of electric heating for freeze protection. Further, collector designs will need to be demonstrated, or developed, which are tolerant of a limited number of freeze/thaw cycles. The candidate salts are also corrosive to the current ball joint sealing materials. This paper outlines the problems which need to be solved before a commercial salt project could reasonably be considered by a project developer, the elements of a test and demonstration program to solve the problems, and the contributions which will be necessary from the salt component vendors, the project developers, and the financial community.
Sandia National Laboratories has completed thermal performance testing on the Schott parabolic trough receiver using the LS-2 collector on the Sandia rotating platform at the National Solar Thermal Test Facility in Albuquerque, NM. This testing was funded as part of the US DOE Sun-Lab USA-Trough program. The receiver tested was a new Schott receiver, known as Heat Collector Elements (HCEs). Schott is a new manufacturer of trough HCEs. The Schott HCEs are 4m long; therefore, two were joined and mounted on the LS-2 collector module for the test. The Schott HCE design consists of a 70mm diameter high solar absorptance coated stainless steel (SS) tube encapsulated within a 125mm diameter Pyrex® glass tube with vacuum in the annulus formed between the SS and glass tube to minimize convection heat losses. The Schott HCE design is unique in two regards. First, the bellows used to compensate for the difference in thermal expansion between the metal and glass tube are inside the glass envelope rather than outside. Second, the composition of materials at the glass-to-metal seal has very similar thermal expansion coefficients making the joint less prone to breakage from thermal shock. Sandia National Laboratories provided both the azimuth and elevation collector module tracking systems used during the tests. The test results showed the efficiency of the Schott HCE to be very similar to current HCEs being manufactured by Solel. This testing provided performance verification for the use of Schott tubes with Solargenix trough collector assemblies at currently planned trough power plant projects in Arizona and Nevada.
Parabolic trough power systems that utilize concentrated solar energy to generate electricity are a proven technology. Industry and laboratory research efforts are now focusing on integration of thermal energy storage as a viable means to enhance dispatchability of concentrated solar energy. One option to significantly reduce costs is to use thermocline storage systems, low-cost filler materials as the primary thermal storage medium, and molten nitrate salts as the direct heat transfer fluid. Prior thermocline evaluations and thermal cycling tests at the Sandia National Laboratories’ National Solar Thermal Test Facility identified quartzite rock and silica sand as potential filler materials. An expanded series of isothermal and thermal cycling experiments were planned and implemented to extend those studies in order to demonstrate the durability of these filler materials in molten nitrate salts over a range of operating temperatures for extended timeframes. Upon test completion, careful analyses of filler material samples, as well as the molten salt, were conducted to assess long-term durability and degradation mechanisms in these test conditions. Analysis results demonstrate that the quartzite rock and silica sand appear able to withstand the molten salt environment quite well. No significant deterioration that would impact the performance or operability of a thermocline thermal energy storage system was evident. Therefore, additional studies of the thermocline concept can continue armed with confidence that appropriate filler materials have been identified for the intended application.
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