Formamidinium lead iodide (FAPbI) perovskite as a superior solar cell material was investigated in two polymorphs at high pressures using in situ synchrotron X-ray diffraction, FTIR spectroscopy, photoluminescence (PL) spectroscopy, electrical conductivity (EC) measurements, and ab initio calculations. We identified two new structures (i.e., Imm2 and Immm) for α-FAPbI but only a structural distortion (in C2/c) for δ-FAPbI upon compression. A pressure-enhanced hydrogen bond plays a prominent role in structural modifications, as corroborated by FTIR spectroscopy. PL measurements and calculations consistently show the structure and pressure dependences of the band gap energies. Finally, EC measurements reveal drastically different transport properties of α- and δ-FAPbI at low pressures but a common trend to metallic states at high pressures. All of these observations suggest strongly contrasting structural stabilities and pressure-tuned optoelectric properties of the two FAPbI polymorphs.
The Ionospheric Continuous‐wave E region Bistatic Experimental Auroral Radar (ICEBEAR) has been reconfigured using a phase error minimization and stochastic antenna location perturbation technique. The resulting 45‐baseline sparse non‐uniform coplanar T‐shaped array, ICEBEAR‐3D, is used for aperture synthesis radar imaging of low elevation targets. The reconfigured receiver antenna array now has a field of view ±45° azimuth and 0°–45° elevation at 0.1° angular resolution. Within this field of view no aliasing occurs. Radar targets are imaged using the Suppressed Spherical Wave Harmonic Transform (Suppressed‐SWHT) technique. This imaging method uses precalculated constant coefficient matrices to solve the integral transform from visibility to brightness through direct matrix multiplication. The method then suppresses image artefacts (dirty beam) due to undersampling by combining brightness maps of differing harmonic order. Measuring elevation angles of targets at low elevations with radar interferometers has been a long standing problem. ICEBEAR‐3D elucidates the underlying misinterpretations of the conventional geometry for vertical interferometry especially for low elevation angles. The proper phase reference vertical interferometry geometry is given which allows radar interferometers to unambiguously measure elevation angles from zenith to horizon without special calibration. The receiver antenna array reconfiguration, Suppressed‐SWHT imaging technique, and proper geometry for vertical interferometry are validated by showing agreement of the meteor trail altitude distribution with numerous data sets from other radars.
We associate new data from icebear, a coherent scatter radar located in Saskatchewan, Canada, with scale‐dependent physics in the ionosphere. We subject the large‐scale icebear 3D echo patterns (treated as 2D point clouds) to a data analysis technique hitherto never applied to the ionosphere, a technique that is widely applied in cosmological red‐shift surveys to characterize the spatial clustering of galaxies. The technique results in a novel method to calculate the spatial power spectral density of the greater ionospheric irregularity field. We compare results from this method to in‐situ plasma density and magnetic field observations from the Swarm mission. We show that there is a remarkable similarity between echo clustering spectra in the E‐region and the field‐aligned current structuring spectrum observed in the F‐region: a clear and characteristic preferred scale (5 km) both in the E‐ and F‐region spectra. We discuss the possibility that this represents evidence of an energy injection into the ionospheric irregularity field via energetic particle precipitation, but offer alternative interpretations with wider connotations for the ionosphere‐magnetosphere system. These findings open new and promising avenues of research for the study of the location of ionospheric scatter echoes with 3D information. It constitutes a novel way to consider the pattern of ionospheric irregularities over wide fields of view when there is an abundance of radar echoes, which allows for the analysis of radar data as point clouds.
The Ionospheric Continuous‐wave E‐region Bistatic Experimental Auroral Radar (ICEBEAR) is a VHF coherent scatter radar that operates with a field‐of‐view centered on 58°N, 106°W and measures characteristics of ionospheric E‐region plasma density irregularities. The initial operations of ICEBEAR utilized a wavelength‐spaced linear receiving array to determine the angle of arrival of the ionospheric scatter at the receiver site. Initially only the shortest baselines were used to determine the angle of arrival of the scatter. This publication uses this linear antenna array configuration and expands on the initial angle of arrival determination by including all the cross‐spectra available from the antenna array to determine both the azimuthal angle of arrival and the azimuthal extent of the incoming ionospheric scatter. This is accomplished by fitting Gaussian distributions to the complex coherence of the signal between different antennas and deriving the azimuthal angle and extent based on the best fit. Fourteen hours of data during an active ionospheric period (March 10, 2018, 0–14 UT) were analyzed to investigate the Gaussian fitting procedure and determine its feasibility for implementation with ICEBEAR. A comparison between mapped scatter, both neglecting azimuthal extent and including azimuthal extent is presented. It demonstrates that the azimuthal extent of the ionospheric E‐region scatter is very important for accurately portraying and analyzing the ICEBEAR measurements.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2025 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.