Monodisperse samaria nanospheres and nanorods have been synthesized from commercial bulk Sm2O3 powders and various capping long-chain alkyl acids (e.g., oleic acid, myristic acid, decanoic acid). The synthesized materials were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy (XPS), Fourier transform IR, thermogravimetric analysis, and N2 adsorption/desorption isotherms was employed to characterize these materials. The results revealed that the synthesis of nanorods consists of two steps of growth: (i) the nanoparticles were formed at relatively low temperature (120−140 °C) by Ostwald ripening and (ii) were followed by oriented attachment of these nanoparticles at higher temperature (160−200 °C) to produce the nanorods (average size of 7 nm × 160 nm). Furthermore, the width of nanorods can be controlled by the length of capping alkyl chain agents; on the basis of the experimental results, it seems that a longer alkyl chain agent leads to thinner nanorods; however, the length of nanorods remains unchanged. For the whole process, the possible Ostwald ripening and oriented attachment mechanisms were also discussed. The XPS results for the calcined nanorods sample shows the presence of two oxidation states, Sm3+/Sm2+ (it is found to be 40% Sm2+), and three components by deconvolution of O 1s peak indicating the defected structure. The surface chemical composition is found to be Sm2O3−x (x = 1.8). We believe that this synthetic method is simple, highly reproducible, inexpensive, and applicable for large-scale production.

No abstract

No abstract

A simple route for the synthesis of a new class of porous metal/metal oxide nanoparticle (NP) materials such as Cu−TiO2, Au−ZrO2, Cu−ZrO2, and Au−TiO2 NPs through the cooperative assembly of presynthesis hydrophobic oleic acid (OA)-capped metal and metal oxide NPs is reported. In such a way, the synergistic interaction between metal and metal oxide NPs has gained significant interest owing to new properties that arise at the metal−metal oxide interface. Various technique including XRD, N2 adsorption/desorption isotherms, FTIR, TEM, XPS, and catalytic test were used to monitor the physicochemical and catalytic properties of these materials. The results revealed that these porous materials exhibit homogeneous dispersion in between metal and metal oxide NPs, high surface area, and narrow interparticle pore size distribution. The catalytic properties of these metal/metal oxide NP solids (even Cu oxide NP catalysts, e.g., no noble metal catalyst) in the CO oxidation reaction are better than those of commercial noble metal catalyst (Pt/Al2O3) and the conventional metal oxide-supported Cu catalysts. Based on this synthesis approach, a variety of nanoporous multicomponent solids of both metal and metal oxide with desired proportions can be synthesized.

No abstract