The influence of water molecule coordination onto the water-aromatic interaction. Strong interactions of water coordinating to a metal ion3

Stacking interactions in the crystal structures of square-planar transition metal complexes from the Cambridge Structural Database with five- and six-membered chelate rings fused with C(6-arom) rings (arom = aromatic) were analyzed. The distribution of distances between the closest C(6-arom)-C(6-arom) and C(6-arom)-chelate contacts shows that in a large fraction of the intermolecular interactions the C(6-arom) ring of one molecule is closer to the chelate than to the C(6-arom) ring of the other molecule. These results indicate a possible preference of the C(6-arom) ring to form stacking contacts with the chelate rings. The preference is ubiquitous and does not depend on the metal type.

No abstract

A promising approach to study chiral molecular recognition is studying two-dimensional (2D) crystallization phenomena on well-defined surfaces via scanning tunneling microscopy (STM). We present studies on different two-dimensional chiral systems and discuss their tendency to undergo enantiomeric separation. A special surface enantiomorphism is observed via STM after adsorption of the enantiomers of a helical aromatic hydrocarbon on Cu(111). Instead of crystallization into homochiral 2D domains on the surface [1], racemic enantiomorphs are observed. In this situation, a small excess of one enantiomer is sufficient to create domains possessing single handedness throughout the entire surface layer [2]. The induction of homochirality by chiral doping has also been observed for succinic acid and achiral (R,S)-tartaric acid [3,4]. Our findings are explained by cooperative interactions between many chiral units, similar to the mechanism of chiral amplification observed in helical polymers and coined as "Sergeant and Soldiers" principle. Another recently observed phenomenon is single enantiomorphism due to chiral conflict. Depending on the handedness of a chiral adduct to a racemic situation suppresses one enantiomorph during crystal growth, but supports the other by forming a quasiracemic solid solution [5].