Solubilities in MeOH-H 2 O mixtures at 298.2 K are reported for a number of salts of mono-and bi-nuclear cobalt(III) complexes. From these solubilities and published single ion transfer chemical potentials, on the TPTB (Ph 4 P + ¼ BPh À 4 ) assumption, transfer chemical potentials have been derived for these mono-and bi-nuclear cobalt(III) complexes. The results and trends are discussed in relation to those for other complexes and ions in these binary aqueous solvent mixtures.

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Solubilities and transfer chemical potentials of carboplatin, cisplatin, iproplatin, and several related platinum complexes have been determined in methanol-water mixtures. The range of solvation behaviour is discussed in relation to possible oral administration of complexes of this type.

Solubilities and solvation of dicyanoiron(II) complexes 113and bis-(1,10-