In the title compound, C25H34O4, one n-hexyl chain of the hex­yloxy group adopts a fully extended all-trans conformation, and the other n-hexyl chain displays disorder with site occupancies of 0.470 (3) and 0.530 (3). The dihedral angle between the benzene rings is 44.5 (3)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds form dimers via crystallographic inversion centres.

In the title compound, C28H18O4·2C3H7NO, the dihedral angle between the benzene rings and the anthracene system is 74.05 (12)°. A crystallographic inversion centre is located in the middle of the anthracene unit. The dimethyl­formamide solvent mol­ecules are partially disordered over two positions of approximately equal occupancy [0.529 (6):0.471 (6)]. Inter­molecular O—H⋯O hydrogen bonds with the major occupancy formamide O atom as acceptor result in the formation of 2:1 solvate–complex aggregates, which are alternately linked to shorter solvate units via weak inter­molecular C—H⋯O contacts generated from the rotational disorder of the formamide O atom (minor occupancy component). Weak C—H⋯π inter­actions between the solvent mol­ecules as the donor and the outer anthracene rings support these contacts in the crystal structure for both disorder components.

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