IIpeAJIOXeHa CTpyKTypa aK-T m H o r o q e q T p a nonmepnaaqmi (Cp,TiEtCl-Y)H+y'B-, ~~nrosaro~qarr KHCJIOT~I JIbmica Y H Y', a T a H x e ~~O T O -HoAoHopHbIe MoneKynhI HB. Zum Mechanismus der Aktivierung homogener katalytischer Systeme vom Ziegler-Typ Die zur Aktivierung homogener katalytischer Systeme fur die Ethylenpolymerisation unter Beteiligung von CpaTiEtCl fuhrenden Prozesse werden betrachtet. Anhand kinetischer Daten und der ,?Al-NMR-Spektren wird fur das aktive Zentrum der Polymerisation die Struktur (Cp,TiEtCl-Y) H+Y'B-vorgeschlagen, die die Lewis-Sauren Y und Y' sowie die Protonendonormolekule HB einbezieht.On the mechanism of activation of homogeneous catalytic systems of Ziegler type Activation processes of homogeneous catalytic systems of ethylene polymerization on the basis of Cp,TiEtCl are analyzed. The kinetic and Z' Al-NMR data lead to the conclusion that the active center of polymerization has the structure (Cp,TiEtCl. Y)H+Y'B-, which involves Lewis acids Y and Y' and the proton-donor molecule HB.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2025 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.