This study investigated occupational risks associated with roadside vulcanizers in Ife Central Local Government Area, Southwestern Nigeria. The objectives of the study included the determination of spatial distribution pattern of vulcanizers, examination of location factors as well as the assessment of risks that vulcanizers were exposed to. High resolution imagery (IKONOS) was downloaded and roads of interest were extracted from the imagery to produce a map of the distribution of vulcanizers. Nearest Neighbour Analysis was carried out to determine the spatial pattern of distribution of vulcanizers in the study are. Factor analysis was carried out to extract most manageable factors of location choice, other descriptive statistics were conducted to determine risks factors that vulcanizers were exposed to in the study area. Results revealed that vulcanizers were distributed in a dispersed pattern in the study area given the Nearest Neighbour Index (NNI) of 3.489. Also, proximity to traffic, distance from home, nearness to motor park, low competition, high traffic volume and opportunity for shelter were extracted factors which contributed a total of 61.314% of variance explained by the variables. However, traffic noise, exposure to weather condition and dust and smoke formed the major risks that vulcanizers were exposed to in the study area. The study concluded that most roadside vulcanizers were exposed to risks and actions be taken to relocate them from roadside to reduce mortality that may arise from unsafe trade location.