By using an existing cut-growth test in a new way it has been possible not only to increase the reproducibility of the results, but also to show important relations between cut-growth resistance and modulus, or the elongation at break of cold SBR tread stocks. The logarithm of the cut-growth resistance of cold SBR vulcanizates as measured on a modified De Mattia machine, is shown to be a linear function of the 300 per cent modulus, except for certain undercured stocks. The slope of the curve is dependent on the type and the amount of black, but is relatively independent of the type of curing system, amount of antioxidant, and time of Geer aging. An equation has been found which relates cut-growth resistance at 150° F with the elongation at break of the vulcanizate. Except for stocks having black loadings in excess of about 55 phr and having in addition modulus values less than 800 psi, this relation appears to be nearly independent of black loading, type of black, curing system, time or temperature of cure, antioxidant concentration, and extent of Geer aging. The elongation at break of an SBR tread stock thus appears to be a primary factor governing its groove-cracking behavior. The relation between cut-growth resistance and modulus is of secondary significance and evidently depends upon the interrelation between the modulus and breaking elongation of these formulations. The breaking elongation, however, cannot be the sole factor governing the groove-cracking behavior; otherwise there would be no restrictions on the validity of the breaking elongation equation.
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