The crystal structure of bis(iminodiacetato)dioxouranium(VI) has been determined by Fourier methods and refined by least-squares calculations to R=0.038. The unit cell is triclinic P]" with a=8-970 (3), b=6.367 (2), c=5-843 (2)~, 0c=92.42 (4), ,8=76.38 (4), y=104.15 (4) °, Z=I. The iminodiacetate ligands are bridging the uranyl groups in infinite chains running in the [0]1] direction, cross-linked through hydrogen bonds. The carboxylate groups are both ionized and the proton is linked to the nitrogen atom. One carboxylate group of each ligand acts as monodentate, the other as bidentate on two adjacent uranium atoms. The geometry around the uranium is approximately hexagonal bipyramidal.