The heat capacity C P ͑T͒ of the ferromagnetic compounds RAl 2 ͑R =Pr,Nd,Tb,Dy,Ho,Er͒ was measured at zero and applied magnetic field of 5 T in the temperature interval from 2 to 200 K. From these results are calculated the magnetic component of the entropy change, −⌬S mag ͑T͒ = S͑0,T͒ − S͑H , T͒. From resistivity measurements, ͑H , T͒, from 2 to 300 K in the same compounds, we calculated the resistivity change due to the applied magnetic field, −⌬ mag ͑T͒ = ͓ mag ͑0,T͒ − mag ͑H , T͔͒. The results are compared and we observed a similar dependence between −⌬ mag ͑T͒ and ͑T / T C ͒ m ⌬S mag ͑T͒ with m = 0 for T ജ T C and m = 1 for T ഛ T C. A simple model using a Hamiltonian considering molecular and crystalline electric fields, in a mean field approximation, is adopted for the calculus. Our results show that theory and experiment are in good agreement showing that the magnetoresistivity is a probe to the field-induced change of magnetic entropy in these compounds and can be extended to other materials. A model for the factor connecting both quantities, −⌬S mag ͑T͒ and −⌬ mag ͑T͒, is developed. This factor contains mainly the effective exchange integral which is related to Fermi energy that in turn is related to the electron effective mass.
The inverse magnetocaloric effect occurs when a magnetic material cools down under applied magnetic field in an adiabatic process. Although the existence of the inverse magnetocaloric effect was recently reported experimentally, a theoretical microscopic description is almost nonexistent. In this paper we theoretically describe the inverse magnetocaloric effect in antiferro- and ferrimagnetic systems. The inverse magnetocaloric effects were systematically investigated as a function of the model parameters. The influence of the Néel and the compensation temperature on the magnetocaloric effect is also analyzed using a microscopic model.
We report on calculations of the anisotropic magnetocaloric effect in DyAl 2 using a model Hamiltonian including crystalline electrical field effects. The anisotropic effect is produced by the rotation of a constant magnetic field from the easy to a hard magnetic direction in the crystal and is enhanced by the first order nature of the field induced spin reorientation transition. The calculated results indicate that for a field with modulus of 2 T rotating from a hard to the easy direction, the isothermal magnetic entropy ͑⌬S iso ͒ and adiabatic temperature ͑⌬T ad ͒ changes present peak values higher than 60% the ones observed in the usual process, in which the field direction is kept constant and the modulus of the field is varied.
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