In present study, the effects of the process parameters on chlorination of Titanium Carbide (TiC) was studied. Besides that, process parameters were investigated by using experimental design of experiment (DOE) and statistical analysis. The chlorination of the samples was carried out at temperatures between 400 to 500°C. Effects of three parameters, namely temperature, soaking time, and molar ratio of potassium permanganate (KMnO4) to hydrochloric acid (HCl) were investigated. The interaction, on the rate of chlorination of TiC were statistically evaluated by using DOE. The weight loss (wt. %) was the main response taken into account in this paper. The results of the experimental design indicated that the main significant factor for chlorination of TiC was higher temperature, soaking time and higher molar ratio of KMnO4 to HCl. DOE results have demonstrated that the highest extent of chlorination obtained at the highest weight loss (wt. %) was about 54.59 wt. % at 500°C with a soaking time of 180 minutes and KMnO4 to HCl molar ratio of 0.17 respectively. The amounted to a titanium extraction of about 96.39 %. On the other hand, the lowest wt. lost was 30.76 wt. % and this was obtained at 500°C for 120 minutes with KMnO4 to HCl molar ratio of 0.09 respectively. The results obtained from this work will be employed as a guide for the future studies on chlorination of nitrided/carburized Malaysian ilmenite or titanium oxycarbonitride. The final aim was to produce TiCl4 at low temperatures (≤500°C) using the latter samples. The experimental values are in good agreement with calculations from the statistical model.

Silica sand from Kandal province, Cambodia and Tapah Perak, Malaysia was grounded into an average micron size of 128.12 and 132.68µm. Both sands were characterized by X-ray fluorescence (XRF), X-ray Diffraction, particle Size Analysis, Differential Thermal Analysis and Thermogravimetric Analysis (DTA/TGA). Malaysian silica sand was designated SDMTP and Cambodian Silica sand as SDCK. From theanalysis, XRF showed that the major impurities in SDMTP were Al2O3, K2O and TiO2. On the other hand, SDCK had impurities of Al2O3,K2O and Na2O. DTA results from SDMTP and SDCK showedthere is an endothermic peak occurring at 572°C which can be attributed to β-quartz transformation into α-quartz. TGA for SDMTP showed that maximum weight lost was at 441°C with a weight percent (wt%) change of 0.48%. The TGA for SDCK showed a wt% change of 1.298% at temperature of 1000°C. From XRD analysis, the main phase of SDCK and SDMTP were quartz. The impurities of both sands play an important role in determining the optical and mechanical properties of the soda lime silicate (SLS) glass formed. Particle size of silica sand affects the mechanical properties such as compression, hardness, and transmittance of SLS glass. The smaller particle size would be ideal choice for glassmaking. Melting temperature, soaking time, and melt accelerant can also affect the mechanical properties of SLS glass. The best result obtained for Vickers hardness in this study was the SLS glass sample designated as Run No 12 with a value of 525.02 kg.mm-2. It had a particle size range from 500-600µm, a furnace soaking time of 4 hours at a melting temperature of 1500°C with 1.0 wt% of Sodium Chloride (NaCl) as meltingaccelerant. On the other hand, the highest compressive strength of 356.22 MPa was found in sample designated as Run No 1. It had a particle size range from 75-1800µm, a soaking time of 5 hours at a melting temperature of 1550°C with 0.5 wt% of NaCl. Lastly,the highest UV-VIS transmittance at 520 nm was obtained from sample designated as Run No 5 within the value of 84.26 %Transmittance (T). It had a particle size range of 75-1800µm, soaking time of 3 hours at a melting temperature of 1550°C with 1.5 wt% of NaCl. .