“Morelos rice” is a variety of rice with certificate of denomination of origin. It is a large grain of opaque appearance and extra large size that is grown exclusively in Morelos state (Mexico). Thus, the quality and characteristics of its rice bran may affect the kinetic of the extraction process of its oil as well as its stability. Therefore, this work is oriented to determine the extraction kinetics of its oil and its oxidative stability. The latter one is obtained through the proposal of a method based on open-circuit potential measurements. The results showed that the rice bran has 21.44% of raw oil, with a chemical composition (based on fatty acids) of 48.48% oleic acid, 35.26% linoleic acid, and 14.54% palmitic acid, as well as a free fatty acid content of 8.15%. A high percentage of its oil content can be recovered in a short time at room temperature, and its extraction kinetics is a function of both the washing and the diffusion of its oil. Under storage conditions the raw oil has a high stability, at least 8 months, and its oxidative stability was of 24, 9, and 7 hours at 50°C, 80°C, and 110°C, respectively.
Due to its high oil content, this research proposes the use of an agroindustrial byproduct (rice bran) as a sustainable option for the synthesis of corrosion inhibitors. From the crude rice bran oil, the synthesis of fatty amide-type corrosion inhibitors was carried out. The corrosion inhibitory capacity of the fatty amides was evaluated on an API X-70 steel using electrochemical techniques such as real-time corrosion monitoring and potentiodynamic polarization curves. As a corrosive medium, a CO2-saturated solution (3.5% NaCl) was used at three temperatures (30, 50, and 70°C) and different concentrations of inhibitor (0, 5, 10, 25, 50, and 100 ppm). The results demonstrate that the sustainable use of agroindustrial byproducts is a good alternative to the synthesis of environmentally friendly inhibitors with high corrosion inhibition efficiencies.
Based on its high oil content, this research proposes the use of an agro-industrial by-product (rice bran) as a sustainable option for the synthesis of environmentally friendly corrosion inhibitors. The extraction and characterization of the raw rice bran oil was carried out, and the imidazoline-type inhibitors were synthesized from a 1:3 molar ratio (oil:aminoethylethanolamine). The corrosion inhibitory capacity of the product obtained was evaluated by electrochemical techniques such as potentiodynamic polarization curves and real-time corrosion monitoring. The inhibitory capacity of the synthesized compound was evaluated on an API X-70 steel using a saline solution (3.5% wt. NaCl) saturated with CO 2 . The evaluation was performed at three temperatures (30, 50 and 70 °C) and different concentrations of inhibitor (0, 5, 10, 25, 50 and 100 ppm). The results showed that the sustainable use of agro-industrial by-products is a good alternative for the synthesis of environmentally friendly corrosion inhibitors with high inhibition efficiencies.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.