A global transition towards more sustainable, affordable and reliable energy systems is being stimulated by the Paris Agreement and the United Nation's 2030 Agenda for Sustainable Development. This poses a challenge for the corrosion industry, as building climate-resilient energy systems and infrastructures brings with it a long-term direction, so as a result the long-term behaviour of structural materials (mainly metals and alloys) becomes a major prospect. With this in mind "Corrosion Challenges Towards a Sustainable Society" presents a series of cases showing the importance of corrosion protection of metals and alloys in the development of energy production to further understand the science of corrosion, and bring the need for research and the consequences of corrosion into public and political focus. This includes emphasis on the limitation of greenhouse gas emissions, on the lifetime of infrastructures, implants, cultural heritage artefacts, and a variety of other topics.
The ISO 11846 Method B is one of the most frequently used corrosion tests to investigate the intergranular corrosion susceptibility of Al‐Mg‐Si(‐Cu) alloys and involves the sample immersion in an aqueous solution containing 30 g/L NaCl and 10 ml/L concentrated HCl for 24 h. Unfortunately, the standard allows for a broad range of parameter variation, for instance the temperature of the test solution and the volume‐to‐surface‐ratio of the solution related to the sample surface area, which causes insufficient reproducibility and reliability of this test method. In the present study, the influence of testing parameter variations within the scope of ISO 11846 Method B on the test results of an almost Cu‐free and a Cu‐containing variant of the 6016 aluminum alloy, both tested in the T4 condition and after a bake‐hardening treatment, was studied in detail. The results show that particularly the volume‐to‐surface‐ratio as well as the surface preparation and the solution temperature significantly influence the test results.
Nowadays, automotive heat exchangers are mainly made from aluminum. Over the last few decades, the development of aluminum brazing sheet has been mainly focused on the improvement of the external corrosion resistance. Recently, the interest of the heat exchanger manufacturers has also moved toward the assessment of the internal corrosion resistance. Accelerated tests are used to simulate in-service conditions. These tests are crucial as they provide information to predict the material and product performance. Various internal corrosion tests have been developed, the so-called 'OY water tests'. Among all companies, the testing parameters can be varied in terms of ion concentrations or pH. Although the OY water tests are constantly being improved, there is so far no common internal corrosion standard as existing for external corrosion assessment. The present work aims at providing better understanding corrosion mechanisms encountered in the OY water media. The role of various elements present in the solution, cupric, chloride, sulfate ions, has been determined. These parameters were assessed via immersion testing. In order to get better understanding of the corrosion mechanism, electrochemical analysis combined with SEM characterization was carried out. The electrochemical analysis enables the understanding of the thermodynamics and kinetics of the corrosion process while immersion tests are performed to quantify the level of corrosion and follow the surface evolution over time.
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