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Dissociative electron capture mass spectra in the range 0-10 eV were registered for the antiviral drugs acridanone and acridanoneacetic acid and its n-hexyl and benzyl esters. The appearance energies (AEs) of fragment negative ions from these and some model compounds (carbazole, acetic acid) were measured. The following thermochemical data were deduced from experiment: electron affinities (EAs) 2.44, 3.08 and 4.12 eV for carbazolyd, 8-oxyacridane and acridanone-N-methyleneacetoxy free radicals, respectively, and DH acid values 324.5 and 320.7 kcalÁmol À1 for acridanoneacetic and 8-hydroxyacridane, respectively. The data for CH 3 COOH were: DH acid (CH 3 COOH) = 343 AE 1 kcalÁmol À1 and EA(CH 3 COO Á ) = 3.31 AE 0.05 eV.Intense formation of RCOO À carboxylate ion from acetic acid, acridanoneacetic acid and its benzyl ester contrasted with the as yet unexplainable absence of this ion in the mass spectra of CH 3 COOEt and of the nhexyl ester of acridanoneacetic acid. It was demonstrated that the [MÀH]À1 ion from acridanone possesses the structure of acridane-8-oxy anion rather than N-centred acridanonide anion. The appearance of some fragment ions at unexpectedly low AEs ( 0) was explained by their formation from free radicals produced thermocatalytically in the instrument. The estimation schemes for the enthalpies of formation of more than 20 free radicals and anions, based on the earlier established regularities, 1,2 are described in detail. Some of the data for known species were revised: DH

The adsorption and ion-exchange properties of thermally expanded graphite with respect to hardness cations and SO 4 2! and Cl ! anions were studied.

This paper considers modern sorption materials for wastewater treatment. The literature data on wastewater treatment with materials based on graphene and chitosan are presented. The production and application of composite sorbents is discussed. It is shown that a promising application of graphene oxide (GO) as a filler enhances the mechanical and sorption properties of the polymer matrix. The biopolymer chitosan (Ch) is a challenging matrix for GO, having unique sorption, chelate-forming, ion-exchange, and complex-forming properties. Composite adsorbents based on graphene oxide and chitosan have a high extraction efficiency of heavy and radioactive metals, dyes, and pharmaceutical compounds dorzolamide and tetracycline. GO-Ch composites with various ratios of chitosan and graphene oxide (2–7%) were formed by drop granulation. The composites obtained were investigated in terms of the ability to extract copper cations from the effluents, and it was shown that the composite having the content of GO:Ch = 55.5:44.5% (by mass in dry granules) had the best sorption and mechanical properties. This sample had high purification efficiency from copper cations (96%) and the required mechanical properties (attrition ≤ 0.4%, grindability ≤ 4%). For this sample, the influence of various factors (pH, sorbent dosage, temperature, and time of sorption) on sorption processes were studied. The best conditions for the sorption processes by the GO-Ch sorbent were determined. The sorbent dosage was 20 g/L, the sorption time was 20 min, and the temperature was 20 ± 2 °C, pH = 7. The adsorption isotherm was plotted and the maximum sorption capacity of copper cations A = 58.5 mg/g was determined. Microstructural and infrared (IR) spectroscopy studies of GO-Ch composites showed the presence of a porous surface and OH- and C=O functional groups. A mechanism for the extraction of copper cations due to physical sorption of the porous surface by GO-Ch composites, and due to chemisorption processes by functional groups, was proposed. The sorption properties for methylene blue and iodine absorption, and the specific surface area of the GO-Ch samples, were determined. The spent sorbent is proposed to be used as a soil improver.