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The paper proposes a mathematical model describing electrooxidation of a polydisperse system of metal nanoparticles from the surface of an indifferent macroelectrode. It is shown that the degree of dispersion of a nanoparticle ensemble affects the shape of oxidation voltammograms. When the degree of dispersion rises and the average size of nanoparticles becomes smaller, the range of oxidation potentials increases. The results of the experimental study of electrooxidation of gold nanoparticles with different degrees of dispersion are given. The particles were localized on the surface of graphite screen-printed electrodes. A good agreement between the parameters of the experimental and calculated voltammograms confirms the correctness of the proposed model.

Abstract The unique properties of nanoparticles make them an extremely valuable modifying material, being used in electrochemical sensors. The features of nanoparticles affect the kinetics and thermodynamics of electrode processes of both nanoparticles and redox reactions occurring on their surface. The paper describes theoretical background and experimental studies of these processes. During the transition from macro- to micro- and nanostructures, the analytical characteristics of sensors modify. These features of metal nanoparticles are related to their size and energy effects, which affects the analytical characteristics of developed sensors. Modification of the macroelectrode with nanoparticles and other nanomaterials reduces the detection limit and improves the degree of sensitivity and selectivity of measurements. The use of nanoparticles as transducers, catalytic constituents, parts of electrochemical sensors for antioxidant detection, adsorbents, analyte transporters, and labels in electrochemical immunosensors and signal-generating elements is described.

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