A method is described for measuring low-energy ignition of combustable mixtures using nanosecond and picosecond laser-induced breakdown. Ignition studies are reported for homogeneous H2/air mixtures. The extent of flame inhibition in H2/air was investigated as a function of CO2 concentration. Our electrodeless spark ignition results are compared with earlier work using electric discharge ignition. A simple model for flame ignition is advanced, based on the temporal and energy density characteristics of the source energy. Implications of laser-induced spark ignition in homogeneous fuel mixtures to the molecular dynamics of flame propagation are discussed.
Techniques based on picosecond resonance-enhanced multiphoton ionization and mass-selective ion photodissociation are described as a means for studying complex reaction mechanisms in molecular clusters. A set of experiments is described that can identify the cluster-size specific reactions that occur by the overlapping processes of neutral dissociation/fragment ionization, parent ionization/dissociation, and parent ion photoexcitation/dissociation. These molecular beam techniques are demonstrated for the case of neutral and ionic photon transfer and evaporation in clusters of phenol in (NH(3))(n), as well for radical chemistry and van der Waals dissociation in (CH(3)I) (n) clusters.
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