In highly out-of-equilibrium states of matter, such as those induced by a pump laser, the applicability of well established spectroscopic probes of magnetic order are called into question. Here we address the validity of magnetic linear dichroism (MLD), a crucial probe of antiferromagnetic order, in pump laser conditions. Employing state-of-the-art time-dependent density-functional theory we compute the dynamics of the square of the spin moment and compare it to that derived spectroscopically via the L3-edge MLD response in two contrasting materials, ferromagnetic FePt and antiferromagnetic FePd. For the latter material the agreement between these distinct routes to the magnetic moment severely degrades for pulse fluences greater than ∼ 1mJ/cm 2 -with errors exceeding a 50% underestimated of moment -indicating a breakdown of the MLD response as a probe of magnetic order. This contrasts with ferromagnetic FePt for which L3 edge MLD reliably tracks magnetism over a broad range of fluences. We attribute this to the increased loss of d-moment to delocalized states under laser pump conditions in an antiferromagnetic environment, and propose that this represents a finding that holds generally for antiferromagnetic materials.