We review the theory and phenomenology of instantons in QCD. After a general overview, we provide a pedagogical introduction to semi-classical methods in quantum mechanics and field theory. The main part of the review summarizes our understanding of the instanton liquid in QCD and the role of instantons in generating the spectrum of light hadrons. We also discuss properties of instantons at finite temperature and the chiral phase transition. We give an overview over the importance of instantons in some other models, in particular two dimensional sigma models, electroweak theory and supersymmetric QCD.Comment: 143 pages, latex (uses rmp.sty, harvard.sty, epsf.sty), 42 figures, to appear in Rev. Mod. Phy

Several approaches to QCD with two massless quarks at finite temperature T and baryon chemical potential mu suggest the existence of a tricritical point on the boundary of the phase with spontaneously broken chiral symmetry. In QCD with massive quarks there is then a critical point at the end of a first order transition line. We discuss possible experimental signatures of this point, which provide information about its location and properties. We propose a combination of event-by-event observables, including suppressed fluctuations in T and mu and, simultaneously, enhanced fluctuations in the multiplicity of soft pions.Comment: 5 pages (published version

The event-by-event fluctuations of suitably chosen observables in heavy ion collisions at CERN SPS, BNL RHIC, and CERN LHC can tell us about the thermodynamic properties of the hadronic system at freeze-out. By studying these fluctuations as a function of varying control parameters, it is possible to learn much about the phase diagram of QCD. As a timely example, we stress the methods by which present experiments at the CERN SPS can locate the second-order critical end point of the first-order transition between quark-gluon plasma and hadron matter. Those event-by-event signatures which are characteristic of freeze-out in the vicinity of the critical point will exhibit nonmonotonic dependence on control parameters. We focus on observables constructed from the multiplicity and transverse momenta of charged pions. We first consider how the event-by-event fluctuations of such observables are affected by Bose-Einstein correlations, by resonances which decay after freeze-out, and by fluctuations in the transverse flow velocity. We compare our thermodynamic predictions for such noncritical event-by-event fluctuations with NA49 data, finding broad agreement. We then focus on effects due to thermal contact between the observed pions and a heat bath with a given ͑possibly singular͒ specific heat, due to the direct coupling between the critical fluctuations of the sigma field and the observed pions. We also discuss the effect of the pions produced in the decay of sigma particles just above threshold after freeze-out on the inclusive pion spectrum and on multiplicity fluctuations. We estimate the size of these nonmonotonic effects, which appear near the critical point, including restrictions imposed by finite size and finite time, and conclude that they should be easily observable.