The nanoscale Li2Mn0.8Ni0.2SiO4/ MnO2 composite was successfully prepared via a two-step method. Firstly, by the preparation of MnO2 nanoparticles through an oxidation-reduction reaction; secondly, by synthesizing Li2Mn0.8Ni0.2SiO4 using the EDTA-assisted...

This study successfully synthesized Li2MnSiO4/Mn3O4 (LMS/M3) and Li2Mn0.8Ni0.2SiO4/Mn3O4 (LMNS/M3) nanocomposites in a two-step method first, by preparing Mn3O4 (M3) nanoparticles through a hydrothermal method and second, by synthesizing Li2MnSiO4 (LMS) and Li2Mn0.8Ni0.2SiO4 (LMNS) by ethylene diamine tetra-acetic assisted sol–gel method. In the last method, the two nanoparticles are mixed by hand-milling to form nanocomposites. Synthesized nanoparticles were characterized using X-ray diffraction, Fourier-transform infrared, Raman spectra, scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, Brunauer–Emmett–Teller surface area, pL and UV–vis spectra measurements. The nanocomposite presents a well-developed orthorhombic crystal structure with a Pmn21 space group. BET surface area measurements indicate that all the prepared materials are mesoporous. The photocatalytic activity of M3, LMS, LMNS, (LMS/M3), and (LMNS/M3) was investigated by the photocatalytic degradation of reactive blue 5 (RB5) under UV light irradiation using a homemade photoreactor. The maximum photodegradation was achieved at optimal pH 4 and photocatalyst dose 0.005 g/50 ml dye. Higher stability for dye degradation efficiency was attained for the LMS and LMNS nanomaterials and LMS/M3 and LMNS/M3 nanocomposites than M3 to photocatalytic activity. The photocatalyst is readily recoverable and shows excellent stability even after three cycles. The photocatalytic degradation for RB5 followed first-order kinetics. Graphical Abstract