Star-shaped carbazole-based compounds were synthesized by the Buchwald−Hartvig method. The materials were examined by various experimental and theoretical methods, including differential scanning calorimetry, UV spectrometry, electron photoemission, time-of-flight techniques, and DFT (B3LYP) calculations. The synthesized compounds showed high thermal stability with the initial weight loss temperature higher than 400 °C. The electron photoemission spectra of the layers of the amorphous materials showed ionization potentials of 4.9 eV. Tri(9hexylcarbazol-3-yl)amine showed high hole mobility (μ = 10 −3 cm 2 V −1 s −1 at an electric field of 3.6 × 10 5 V/cm). The starshaped compounds were used for the preparation of bilayer white organic light-emitting diodes which combine emission from both excitons and exciplexes. The brightness of the white organic light emitting diode at 7 V is 300 cd/m 2 with current efficiency 2.3 cd/A and CIE coordinates (0.37, 0.35) which are very close to the equienergy white point (0.33, 0.33).

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