Advanced oxidation procedures (AOPs) refer to a variety of technical procedures that produce OH radicals to sufficiently oxidize wastewater, organic pollutant streams, and toxic effluents from industrial, hospital, pharmaceutical and municipal wastes. Through the implementation of such procedures, the (post) treatment of such waste effluents leads to products that are more susceptible to bioremediation, are less toxic and possess less pollutant load. The basic mechanism produces free OH radicals and other reactive species such as superoxide anions, hydrogen peroxide, etc. A basic classification of AOPs is presented in this short review, analyzing the processes of UV/H2O2, Fenton and photo-Fenton, ozone-based (O3) processes, photocatalysis and sonolysis from chemical and equipment points of view to clarify the nature of the reactive species in each AOP and their advantages. Finally, combined AOP implementations are favored through the literature as an efficient solution in addressing the issue of global environmental waste management.
Ultrasound (US) technology is already into the research field providing a powerful tool of producing nanomaterials or being implicated in decoration procedures of catalyst supports for energy applications and material production. Toward this concept, low or/and high-frequency USs are used for the production of nanoparticles, the decoration of catalytic supported powders (carbon-based, titania, and alumina) with nanoparticles, and the production of metal-organic frameworks (MOFs). MOFs are porous, crystalline materials, which consist of metal centers and organic linkers. Those structures demonstrate high surface area, open metal sites, and large void space. All the above produced materials are used in heterogeneous catalysis, electrocatalysis, photocatalysis, and energy storage. Batteries and fuel cells are popular systems for electrochemical energy storage, and significant progress has been made in nanostructured energy materials in order to improve these storage devices. Nanomaterials have shown favorable properties, such as enhanced kinetics and better efficiency as catalysts for the oxygen reduction reaction (ORR).
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