The paper addresses Brownian motion in the logarithmic potential with time-dependent strength, U(x, t) = g(t)log(x), subject to the absorbing boundary at the origin of coordinates. Such model can represent kinetics of diffusion-controlled reactions of charged molecules or escape of Brownian particles over a time-dependent entropic barrier at the end of a biological pore. We present a simple asymptotic theory which yields the long-time behavior of both the survival probability (first-passage properties) and the moments of the particle position (dynamics). The asymptotic survival probability, i.e., the probability that the particle will not hit the origin before a given time, is a functional of the potential strength. As such, it exhibits a rather varied behavior for different functions g(t). The latter can be grouped into three classes according to the regime of the asymptotic decay of the survival probability. We distinguish 1. the regular (power-law decay), 2. the marginal (power law times a slow function of time), and 3. the regime of enhanced absorption (decay faster than the power law, e.g., exponential). Results of the asymptotic theory show good agreement with numerical simulations.
Statistical description of stochastic dynamics in highly unstable potentials is strongly affected by properties of divergent trajectories, that quickly leave metastable regions of the potential landscape and never return. Using ideas from theory of Q-processes and quasi-stationary distributions, we analyze position statistics of nondiverging trajectories. We discuss two limit distributions which can be considered as (formal) generalizations of the Gibbs canonical distribution to highly unstable systems. Even though the associated effective potentials differ only slightly, properties of the two distributions are fundamentally different for all highly unstable system. The distribution for trajectories conditioned to diverge in an infinitely distant future is localized and light-tailed. The other distribution, describing trajectories surviving in the meta-stable region at the instant of conditioning, is heavy-tailed. The exponent of the corresponding power-law tail is determined by the leading divergent term of the unstable potential. We discuss different equivalent forms of the two distributions and derive properties of the effective statistical force arising in the ensemble of nondiverging trajectories after the Doob h-transform. The obtained explicit results generically apply to non-linear dynamical models with meta-stable states and fast kinetic transitions.
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