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Polymers comprised of redox-active organic radicals have emerged as promising materials for use in a variety of organic electronics, including fast-charging batteries. Despite these advances, relatively little attention has been focused on the diversification of the families of radicals that are commonly incorporated into polymer frameworks, with most radical polymers being comprised of nitroxide radicals. Here, we report two new examples prepared via ring-opening methathesis polymerization containing 6-oxoverdazyl and nitronyl nitroxide radicals appended to their backbones. The polymerization reaction and optoelectronic properties were explored in detail, revealing high radical content and redox activity that may be advantageous for their use as semiconducting thin films. Initial studies revealed that current-voltage curves obtained from thin films of the title polymers exhibited memory effects making them excellent candidates for use in resistive memory applications.Given the rejuvenated interest in the study of radical polymers as semiconducting materials and the promise of examples exhibiting ambipolar redox properties in a variety of applications, we report the synthesis, characterization, and thin-film properties of two new polymers prepared using a radical-tolerant ring-opening metathesis polymerization (ROMP) reaction. Such structural elaboration is essential for further progression of the stable radical polymer research field and the applications it targets.Additional supporting information may be found in the online version of this article. † These authors contributed equally.

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Anodic aluminum oxide is a well-known template for nanofabrication. Structural features of anodic aluminum oxide, such as pore diameter, can be controlled by adjusting anodization operating conditions. In this paper we will describe how nanoporous alumina of different porosities was prepared using electrochemical anodization. The influence of anodization time, potential, and temperature on the formation of well-ordered porous anodic aluminum oxide was studied. Results from high-resolution field-emission scanning electron microscopy have shown that pore diameter increases with increasing potential, temperature, and anodization time. Optimal anodic aluminum oxide pore diameter and arrangement were obtained for samples anodized at 40 V, 30°C for 60 min.

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