Determining the nature, evolution, and impact of acid‐generating sulfur deposits in the Mary Rose wooden hull is crucial for protecting Henry VIII's famous warship for generations to come. Here, a comprehensive X‐ray absorption near‐edge spectroscopy (XANES) and X‐ray fluorescence (XRF) study sheds vital light on the evolution of complex sulfur‐based compounds lodged in Mary Rose timbers as a function of drying time. Combining insights from infrared spectroscopy correlates the presence of oxidized sulfur species with increased wood degradation via the loss of major wood components (holocellulose). Intriguingly, zinc is found to co‐exist with iron and sulfur in the most degraded wood regions, indicating its potential contributing role to wood degradation. This study provides crucial information on the degradation processes and resulting products within the wood, which can be used to develop remediation strategies to save the Mary Rose.
If left to dry uncontrollably following excavation, marine archaeological wood suffers significant and irreparable damage. Conservation treatments are required to consolidate degraded wood and to remove residual water. Drying must be controlled to eliminate erratic and heterogeneous water removal. Monitoring and understanding the drying process progression is invaluable information to garner real-time knowledge to correlate with chemical and physical material properties, and to develop future conservation strategies. Here, polyethylene glycol (PEG) consolidated marine archaeological wood was periodically sampled during drying to determine the moisture content as a function of location, time, and sample depth. The heterogeneous nature of the material leads to significant noise across spatial and temporal measurements, making it challenging to elucidate meaningful conclusions from visual observation of the raw data. Therefore, the spatiotemporal data was computationally analysed to produce a representative model of the ship’s drying, illustrated by a dynamic simulation. From this we can quantitatively predict the drying rate, determine the depth-dependence of drying, and estimate the resulting equilibrium moisture content. This is the first time such simulations have been carried out on this material and conservation process, demonstrating the power of applying numerical modelling to further our understanding of complex heritage data.
The Cover Feature shows the Tudor warship, the Mary Rose, which is on display in Portsmouth (UK). Her conservation involved drying in an environmentally controlled enclosure. To understand the impact of exposure to air on the ancient timbers, samples were removed and analysed with spectroscopic techniques. From this it was possible to link the presence and evolution of sulfur and iron to wood degradation, thereby providing crucial information for future conservation strategies. More information can be found in the Full Paper by E. J. Schofield and co‐workers (DOI: 10.1002/cplu.202000160). Photo credits: Stephen Foote, Mary Rose Trust; and Diamond Light Source.
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