The biostratigraphy and paleoenvironments of the İhsaniye Formation exposed at Karaburun in northwest Turkey is described based upon the study of abundant and well-preserved foraminifera, calcareous nannofossils and palynomorphs. The studied succession is Early Oligocene in age, with calcareous nannofossil zones upper NP21 (Subzone CNO1) to lower NP23 (Subzone CNO3) and planktonic foraminifera zones O1 (~P18) and O2 (~P19) represented, and palynological assemblages suggestive of zones D13 to D14a. Based on these new data, a revised interpretation of the stratigraphic succession is presented. Deposition was controlled by a now inverted normal fault, with deposition of older stratigraphy (upper NP21 to NP22) restricted to the original hanging wall. During NP23, deposition commenced on the footwall, resulting in progressive onlap of an exposed Eocene reefal limestone (Soğucak Formation). Three primary sedimentary facies are present: marls with thin calcareous siltstones, marls with synsedimentary slumps and debris flows, and coarse pebbly sandstones. The coarse pebbly sandstones were deposited in a fan-delta/shoreface paleoenvironment and represent the initial phase of onlap during biozone NP23 onto a rocky shoreline on the footwall side of the fault. The marl-dominated facies represent deposition in outer shelf-upper bathyal environments. The succession demonstrates evidence for a near-end Eocene relative sea-level fall. Changes in the abundance of planktonic foraminifera and the onlap onto the footwall demonstrate maximum subsequent transgression within NP23. This reflects eustasy rather than Paratethyan relative sea-level. No interpretation of sea-water salinity reduction can be made for the sediments deposited during biozone NP23 in the studied sections, although this is noted in coeval sediments in parts of Paratethys (the "Solenovian Event"). Together with the open marine nature of the diverse and abundant fossil assemblages, it is suggested that deposition of the Karaburun section was strongly influenced by a connection to the global ocean, via the Çatalca Gap, as suggested in a recent study.
The Lower Oligocene succession of the İhsaniye Formation, exposed at Karaburun on the Turkish (Thrace) coast of the Black Sea, provides insights into potential hydrocarbon source rock extent in the southwestern part of the Black Sea Basin. Presently, no detailed study of the İhsaniye Formation exists with regards to organic matter content and type. We analyzed 78 fine-grained samples from a c. 70-m-thick section near Karaburun. Relatively high total organic carbon (TOC) contents (average 1.45 wt.%) are present in the lower part of the İhsaniye Formation; the hydrogen index values reach a maximum of 252 mg HC/g TOC, indicating the presence of type III-II kerogen, and the organic matter is thermally immature (T max 418 °C). The presence of foraminifera and TOC/S ratios below 2.8 confirm a fully marine environment. Elevated TOC contents and very low pristane/phytane ratios indicate an oxygen-depleted environment during deposition of the lower part of the İhsaniye Formation. The quartz/clay minerals ratio suggests a deepening trend in the lower part of the succession and a shallowing trend in the upper part. Peculiarly, the low salinity "Solenovian Event" (in nannofossil zone NP23) is not developed although Sr isotope ratios indicate that the basin was only connected to the Mediterranean for short periods during deposition of the İhsaniye Formation.
The Oligocene Ruslar Formation, an equivalent of the Maykop Suite, is a potential hydrocarbon source rock in the western Black Sea Basin. In contrast to the offshore areas, the depositional environment and hydrocarbon source rock potential of onshore Bulgaria sediments are largely unknown. Hence, a 14-m-thick section of the Ruslar Formation, exposed near Karadere (Black Cape) along the Black Sea coast, provides an excellent opportunity to study the upper part of the Ruslar Formation. Here, laminated diatomrich mudstones with frequent thin sandstone beds and a prominent concretion horizon are exposed. Furthermore, the fossil diatom assemblages provide a key component to understand the paleoenvironment. Overall, Paleogene diatoms are understudied in the Black Sea Basin and therefore only a genus-level study is undertaken here. The studied Ruslar Formation contain remarkably diverse and wellpreserved diatom assemblage with 23 different genera. The most frequent genera are Paralia, Distephanosira, and Stephanopyxis. Common genera include Coscinodiscus, Hemiaulus, Pseudopodosira, Rouxia, and Xanthiopyxis. Rare taxa include Actinoptychus,
Diatomaceous sediments are often prolific hydrocarbon source rocks. In the Paratethys area, diatomaceous rocks are widespread in the Oligo-Miocene strata. Diatomites from three locations, Szurdokpüspöki (Hungary) and Limberg and Parisdorf (Austria), were selected for this study, together with core materials from rocks underlying diatomites in the Limberg area. Bulk geochemical parameters (total organic carbon [TOC], carbonate and sulphur contents and hydrogen index [HI]) were determined for a total of 44 samples in order to study their petroleum potential. Additionally, 24 samples were prepared to investigate diatom assemblages.The middle Miocene diatomite from Szurdokpüspöki (Pannonian Basin) formed in a restricted basin near a volcanic silica source. The diatom-rich succession is separated by a rhyolitic tuff into a lower non-marine and an upper marine layer. An approximately 12-m thick interval in the lower part has been investigated. It contains carbonate-rich diatomaceous rocks with a fair to good oil potential (average TOC: 1.28% wt.; HI: 178 to 723 mg HC/g TOC) in its lower part and carbonate-free sediments without oil potential in its upper part (average TOC: 0.14% wt.). The composition of the well-preserved diatom flora supports a near-shore brackish environment. The studied succession is thermally immature. If mature, the carbonate-rich part of the succession may generate about 0.25 tons of hydrocarbons per square meter. The diatomaceous Limberg Member of the lower Miocene Zellerndorf Formation reflects upwelling along the northern margin of the Alpine-Carpathian Foreland. TOC contents are very low (average TOC: 0.13% wt.) and demonstrate that the Limberg Member is a very poor source rock. The same is true for the underlying and over-lying rocks of the Zellerndorf Formation (average TOC: 0.78% wt.). Diatom preservation was found to differ considerably between the study sites. The Szurdokpüspöki section is characterised by excellent diatom preservation, while the diatom valves from Parisdorf/Limberg are highly broken. One reason for this contrast could be the different depositional environments. Volcanic input is also likely to have contributed to the excellent diatom preservation in Szurdokpüspöki. In contrast, high-energy upwelling currents and wave action may have contributed to the poor diatom preservation in Parisdorf. The hydrocarbon potential of diatomaceous rocks of Oligocene (Chert Member; Western Carpathians) and Miocene ages (Groisenbach Member, Aflenz Basin; Kozakhurian sediments, Kaliakra canyon of the western Black Sea) has been studied previously. The comparison shows that diatomaceous rocks deposited in similar depositional settings may hold largely varying petroleum potential and that the petroleum potential is mainly controlled by local factors. For example, both the Kozakhurian sediments and the Limberg Member accumulated in upwelling environments but differ greatly in source rock potential. Moreover, the petroleum potential of the Szurdokpüspöki diatomite, the Chert Member and the Groisenbach Member differs greatly, although all units are deposited in silled basins.
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