Tree retention practices promoting biodiversity may reshape future boreal forest production landscapes. Using the Heureka system, scenarios of 0%, 5%, and 20% retained patches at the stand level were projected over 200 years in a 533 ha boreal landscape. Visualizations of future forest states at a landscape scale and a more detailed scale were made based on the projections. The no retention results in no forest >120 years old, and no large trees (diameter at breast height >40 cm for conifers and >35 cm for broadleaved trees) 100 years from now. With retention levels of 5% and 20%, the area of old forest will comprise 7% and 19% of the total area, respectively. The average number of large trees per ha will be 4 and 13, respectively. Deadwood volumes will be 2.5 times higher at 5% retention and 4 times higher at 20% retention compared to no retention. Landscape visualizations indicate that retention patches covering 5% will marginally modify the visual impression, compared to clear-cuts, while 20% cover will create a much more varied landscape. We conclude that the retention approach is essential for restoring natural conditions. Landscape transformation will be slow and depend on starting conditions and retention levels.
Polycyclic aromatic hydrocarbons (PAH) are common components of many materials, such as petroleum and various types of tars. They are generally present in mixtures, occurring both naturally and as byproducts of fuel processing operations. It is important to understand the thermodynamic properties of such mixtures in order to understand better and predict their behavior (i.e., fate and transport) in the environment and in industrial operations. To characterize better the thermodynamic behavior of PAH mixtures, the phase behavior of a binary (anthracene + phenanthrene) system was studied by differential scanning calorimetry, X-ray diffraction, and the Knudsen effusion technique. Mixtures of (anthracene + phenanthrene) exhibit non-ideal mixture behavior. They form a lower-melting, phenanthrene-rich phase with an initial melting temperature of 372 K (identical to the melting temperature of pure phenanthrene) and a vapor pressure of roughly lnP/Pa = −2.38. The phenanthrene-rich phase coexists with an anthracene-rich phase when the mole fraction of phenanthrene (xP) in the mixture is less than or equal to 0.80. Mixtures initially at xP = 0.90 consist entirely of the phenanthrene-rich phase and sublime at nearly constant vapor pressure and composition, consistent with azeotrope-like behavior. Quasi-azeotropy was also observed for very high-content anthracene mixtures (2.5 < xP < 5) indicating that anthracene may accommodate very low levels of phenanthrene in its crystal structure.
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