The applicability of Bordetella sp. Sulf-8 to degrade Hydrogen Sulfide (H(2)S) gas in a biotrickling system was investigated. The isolate is a heterotrophic gram-negative, catalase- and oxidase-positive, rod-shaped bacterium which can metabolize thiosulfate or sulfide into sulfate. The mesophilic Bordetella sp. Sulf-8 can grow within a wide pH range using yeast as carbon source, with or without the presence of sulfur. In batch experiments, kinetic constants such as maximum specific growth rate (μ (max) = 0.12 1/h), saturation constant (K (S) = 0.017 g/L), and specific sulfur removal rate (88 mg S/g cells h) were obtained. In biotrickling experiments removal efficiencies were satisfactory, but the system performance was observed to be more influenced by empty bed residence time than by H(2)S feed gas concentration. Critical and maximum elimination capacities were 78.0 and 94.5 g H(2)S/m(3) day, respectively. Macrokinetic analysis of the biotrickling system revealed maximum H(2)S removal rate V (max) = 15.97 g S/kg media-day and half saturation constant K (S') = 12.45 ppm(v).
Chromium is one of the heavy metals that significantly affect water quality in Mongolia. The present study is focused on the remediation of surface water contaminated with chromium (III) by a permeable barrier in order to prevent sediment pollution. The adsorption capacity of the selected materials (13X zeolite and vermiculite) was investigated at different sorbent dosages, pH and initial Cr(III) concentration. The equilibrium adsorption studies showed that vermiculite has a higher Cr(III) removal efficiency in comparison with 13X zeolite. A fungal isolate obtained from the sediment samples collected near Tuul River (Mongolia) was selected from enriched Luria-Bertani medium, showing a good performance for Cr(III) removal (78.2% for an initial concentration of 50 mg/L). The fungal isolate was genetically typed by DNA sequencing and was identified as belonging to the Alternaria alternata species. 13X zeolite showed the best performance for Cr removal in the permeable barrier assays compared to vermiculite, achieving a total removal of 96% and a global uptake of 2.49 mg/g. After 13 days of operation none of the barriers reached saturation with chromium.
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