A high sensitive sensor is demonstrated by exploiting strong transverse magneto-optical Kerr effect on a ferromagnetic surface plasmon grating. The surface plasmon grating, made of a hybridized Au/Fe/Au layer, exhibits a very dispersive Kerr parameter variation near the surface plasmon polariton (SPP) wavelength via coherent scattering of the SPP on the grating structure. Interrogating this Kerr parameter can be utilized for detecting chemical or biological objects in a fluid medium. The experiment results show the minimal detectable mass concentration of sodium chloride in a saline solution is 4.27 × 10(-3) %, corresponding to a refractive index change of 7.60 × 10(-6) RIU. For an avidin-biotin interaction experiment, the sensitivity of avidin detection in PBS solution is 1.97 nM, which is limited by the index fluctuation of flowing media during measurement.
Diffusion-ordered NMR spectroscopy (DOSY) presents an
essential
tool for the analysis of compound mixtures by revealing intrinsic
diffusion behaviors of mixed components. The applicability of DOSY
measurements on complex mixtures is generally limited by the performance
of data reconstruction algorithms. Here, based on constraints on low
rank and sparsity of DOSY data, we propose a reconstruction method
to achieve high-resolution DOSY spectra with excellent peak alignments
and accurate diffusion coefficients for measurements of complex mixtures
even when component signals are congested and mixed together along
the spectral dimension. This proposed method is robust and suitable
for DOSY data acquired from common commercial NMR instruments; thus,
it may broaden the scope of DOSY applications.
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