The internal crossfire of ionic and electronic effects in perovskite devices forms a complex analysis problem that has not been fully solved yet. Specifically, halide photovoltaic perovskites show a photoinduced ionic inductance behavior in current transient measurements, evidenced by ubiquitous negative spikes. Here, we provide a consolidated interpretation of these observed chemical mechanisms by independent measurement routes (frequency and time domain) in order to solve an elusive topic in the development of perovskite solar cells for more than a decade. From this operational pathway, we specifically study the light-dependent negative overshoot photocurrent phenomena in the time-domain discharge of the chemical inductor, which is a transversal mechanism found in a multitude of chemical, biological, and material systems. Our results establish a general framework to understand the inductive transient effects observable in new and important applications of halide perovskites, capable of emulating the electrical activity of neurons and synapses when acting as memristors.

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The current interruption method allows a real-time estimation of the physiological state of tissues from their electrical properties.

Capacitive response at long time scales seems to remain an elusive feature in the analysis of the electrical properties of perovskite‐based solar cells. It belongs to one of the critical anomalous effects that arises from the characteristic phenomenology of this type of emerging photovoltaic devices. Thereby, accurately deducing key capacitance feature of new light harvesting perovskites from electrical measurements represents a significant challenge regarding the interpretation of physical processes and the control of undesired mechanisms, such as slow dynamic effects and/or current density–voltage (J–V) hysteresis. Herein, it is shown that long timescale mechanisms that give rise to hysteresis in stable and high‐efficiency quadruple‐cation perovskites are not due to a classical capacitive behavior in the sense of ideal charge accumulation processes. Instead, it is a phenomenological consequence of slow memory‐based capacitive currents and the underlying cooperative relaxations. A fractional dynamics approach, based on the idea of capacitance distribution in perovskite devices, reliably models the slow transient phenomena and the consequent scan‐rate‐ and bias‐dependent hysteresis. Observable for a wide variety of photovoltaic halide perovskites, distributed capacitive effects are rather universal anomalous phenomena, which can be related to the long‐time electrical response and hysteresis.

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