Fe, N)-codoped TiO2 were prepared by calcining the Fe-doped TiO2 samples accomplished by precipitation method in the nitrogen atmosphere, and the photocatalytic properties of (Fe, N)-codoped TiO2 at different temperatures were investigated. The samples were characterized by X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and ultraviolet-visible (UV-vis). The results show that the (Fe, N)-codoped TiO2 powder samples calcined at 600°C are dispersed well with more hydroxyl groups on its surface. The absorption edge of the (Fe, N)-codoped TiO2 is 429nm due to the effects of mixed crystal, which means the improvement of photocatalytic capability.

The porous ceramic biologic films were prepared on the surface of Ti6Al4V (TC4) with micro-arc oxidation technology (MAO). The phase composition, microstructure and cross section morphology, surface elements composition and valence state of micro-arc oxide films were studied. Results show that with increasing of the micro-arc oxidation voltage, the better biocompatible hydroxyapatite appears on the surface of titanium alloy (TC4). The high voltage promotes the surface pore size enlarge.

Microstructures and crystal structures of the second phases YNbO4 and YTiNbO6 in (Y,Nb)-codoped TiO2 ceramics were investigated at different sintering temperature and calcination temperature. The (Y,Nb)-codoped TiO2 ceramics and the second phase ceramic samples were prepared by the traditional electronic ceramic process. The microstructure, chemical composition and crystal structures of samples were characterized by SEM, EDS and XRD. The results show that there exist second phases of YNbO4 and YTiNbO6 in (Y,Nb)-codoped TiO2 ceramic. With the sintering temperature and calcination temperature rising, the second phase YNbO4 will transmit to YTiNbO6.

The effect of thermal oxidation temperature on the properties of MAO ceramic coating was investigated, The phase composition and surface morphology of composite oxidation coating were analyzed by XRD and SEM. The micro-hardness of composite oxidation coating were tested by micro hardness tester. The results shown that the composite oxidation coating consists of rutile, anatase Ti and HA. With the thermal oxidation temperature increasing, the micro-hardness of composite oxidation coatings were improved, but when the thermal oxidation temperature rose from 600 °C to 700 °C, the micro-hardness of coating dropped from 575 HV to 505 HV. With the thermal oxidation temperature increasing, the numbers of micro-porous on coating surface was decreased , and the composite oxidation coating became more density.

The porous ceramic biologic films were prepared on the surface of Ti6Al4V (TC4) with micro-arc oxidation technology (MAO). The phase composition, microstructure and valence state of micro-arc oxide films were studied. The biological properties of the ceramic film were comprehensive evaluated through animal experiments. Results show that with increasing of the micro-arc oxidation voltage, the better biocompatible hydroxyapatite appears on the surface of titanium alloy (TC4). The high voltage promotes the surface pore size enlarge. The porous ceramic surface makes bone tissue early grow up. Pathological sections of bone tissue 24 w animal experiments indicates that the implants can form good biological combination with bone, no rejection and the higher the micro-arc oxidation voltage, the more new bone cells.