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SYNOPSISThe presence of wall slip during the flow of polymeric melts has significant ramifications on the melts' processability. In this study, the effects of materials of construction and surface roughness on the wall slip behavior of a linear low density polyethylene were investigated, using capillary flow. Capillaries, constructed from copper, stainless steel, aluminum, and glass, were used. The inner surface roughness of the capillaries were characterized by the employment of a profilometer and scanning electron microscopy. The roughness profiles of copper capillaries were also altered by the employment of chemical etching. Using Mooney's analysis, the wall slip velocity values were determined to be in the range of 0.09 to 1.34 mm/s. The wall slip velocity values were the highest for stainless steel and were negligible for aluminum. The relative work of adhesion values of polyethylene were the smallest for stainless steel and copper and the highest for glass. Overall, the wall slip velocity values increased with decreasing surface roughness of the capillaries and with decreasing work of adhesion.