A sol-gel chemistry-based method was developed for the preparation of highly stable capillary gas chromatography (GC) columns with surface-bonded poly(ethylene glycol) (PEG) stationary phase. Through a single-step procedure, it concurrently provided column deactivation, stationary-phase coating, and chemical immobilization of the coated film. Sol-gel reactions were carried out within fused-silica capillaries that were filled with properly designed sol solutions containing two sol-gel precursors, two different triethoxysilyl-derivatized poly(ethylene glycol)s, two sol-gel catalysts, and a deactivation reagent. Hydrolytic polycondensation reactions led to the formation of a sol-gel coating chemically bonded to the inner walls of the capillary. A number of sol-gel coated fused-silica capillary columns were prepared using sol-gel-active PEG derivatives. These columns demonstrated many inherent advantages, the main being the strong anchoring of the coating to the capillary wall resulting from chemical bonding with the silanol groups on the fused-silica capillary inner surface. This chemical bonding yielded strongly immobilized PEG coatings with outstanding thermal stability (up to 320 degrees C). To our knowledge, such a high thermal stability has not been achieved so far on conventionally prepared PEG GC columns. Sol-gel PEG columns provided excellent chromatographic performances: high number of theoretical plates, excellent run-to-run and column-to-column reproducibility, and pronounced selectivity for a wide range of test solutes. Using n-octadecane as a test solute (k = 7.14), an efficiency value of 3200 theoretical plates/m was obtained on a 10 m x 0.25 mm i.d. fused-silica capillary column. Five sol-gel PEG columns provided RSD values of 1.09% for column efficiency (solute, n-octadecane), 1.37% for retention factor (solute, n-octadecane), and 0.9% for separation factor (for solute pair o- and p-xylene). In five replicate measurements using the same column, RSD values of less than 0.50% for the retention time and 1.36% for retention factor (k) were obtained.

Human teams are able to easily perform collaborative manipulation tasks. However, for a robot and human to simultaneously manipulate an extended object is a difficult task using existing methods from the literature. Our approach in this paper is to use data from human-human dyad experiments to determine motion intent which we use for a physical humanrobot co-manipulation task. We first present and analyze data from human-human dyads performing co-manipulation tasks. We show that our human-human dyad data has interesting trends including that interaction forces are non-negligible compared to the force required to accelerate an object and that the beginning of a lateral movement is characterized by distinct torque triggers from the leader of the dyad. We also examine different metrics to quantify performance of different dyads. We also develop a deep neural network based on motion data from human-human trials to predict human intent based on past motion. We then show how force and motion data can be used as a basis for robot control in a human-robot dyad. Finally, we compare the performance of two controllers for human-robot co-manipulation to human-human dyad performance.

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MEDICAL MEMORANDA MEDICAL JOURUAL Primary Syncope.-We had one fatal case of this in a girl aged 3 with some history of bronchitis; she was being anaesthetized for a hernia operation. The case resembled in every way the well-known primary syncope of chloroform anaesthesia, and we attribute this to the same mechanism of vagal inhibition. Sugar Metabolism.-We were able to have blood-sugar estimations in only 3 cases. In each there was a rise after 30 to 45 minutes, but much less than that recorded for chloroform or ether by Hewer (1939). Acetone was found in the urine on the mnorning following operation in 23 of 68 cases, in none of which had ether been used. This is in striking contrast to Hewer's report that he did not find acetonuria in any case at all. Post-operative Vomiting.-This was absent in 52 out of 80 cases, and slight in the-remaining 28.