The aim of this paper was the recovering of the cathodic material from discarded lithium ion batteries for obtainment of the lamellar double hydroxides (LDHs) by the co-precipitation method at variable pH in HCl and H 2 O 2 1:1 (v/v) acid solution containing Co and Al (extracted from cathodic material composed of LiCoO 2 and aluminum foil). These metals were precipitated in LiOH at pH 9 or 11, or NH 4 OH at pH 9 and submitted to the hydrothermal treatment (HT) to improve the structural organization of the LDHs lamellae. After precipitation, the resulting solids were structurally characterized by XRD for phase identification and calculation of the unit cell parameter, thermally by TGA for the identification of the mass loss and morphologically by SEM. The sample obtained by precipitation with LiOH at pH 11 / hydrothermal treatment showed diffraction peaks similar to hydrotalcite, morphological and thermal characteristics similar to the pattern Co-Al-Cl LDH obtained by co-precipitation at constant pH 8. Keywords: lithium ion batteries, LiCoO 2 and aluminum foil recovering, reprocessing of cellular phone battery and lamellar double hydroxides