No abstract

The water cycle in urban and hydrologically managed settings is subject to perturbations that are dynamic on small spatial and temporal scales; the effects of which may be especially profound in soils. We deploy a membrane inlet-based laser spectroscopy system in conjunction with soil moisture and temperature sensors to monitor soil water dynamics and H and O stable isotope ratios (δ 2 H and δ 18 O values) in a seasonally irrigated urban-landscaped garden soil over the course of 9 months between the cessation of irrigation in the autumn and the onset of irrigation through the summer. We find that soil water δ 2 H and δ 18 O values predominately reflect seasonal precipitation and irrigation inputs. A comparison of total soil water by cryogenic extraction and mobile soil water measured by in situ water vapor probes reveals that initial infiltration events after long periods of soil drying (the autumn season in this case) emplace water into the soil matrix that is not easily replaced by, or mixed with, successive pulses of infiltrating soil water.Tree stem xylem water H and O stable isotope composition did not match that of available water sources. These findings suggest that partitioning of soil water into mobile and immobile "pools" and resulting ecohydrologic separation may occur in engineered and hydrologically managed soils and not be limited to natural settings. The laser spectroscopy method detailed here has potential to yield insights in a variety of critical zone and vadose zone studies, potential that is heightened by the simplicity and portability of the system.

Stable isotope ratios of H and O are widely used to identify the source of water, e.g., in aquifers, river runoff, soils, plant xylem, and plant-based beverages. In situations where the sampled water is partially evaporated, its isotope values will have evolved along an evaporation line (EL) in δH/δO space, and back-correction along the EL to its intersection with a meteoric water line (MWL) has been used to estimate the source water's isotope ratios. Here, we review the theory underlying isotopic estimation of source water for evaporated samples (iSW). We note potential for bias from a commonly used regression-based approach for EL slope estimation and suggest that a model-based approach may be preferable if assumptions of the regression approach are not valid. We then introduce a mathematical framework that eliminates the need to explicitly estimate the EL-MWL intersection, simplifying iSW analysis and facilitating more rigorous uncertainty estimation. We apply this approach to data from the US EPA's 2007 National Lakes Assessment. We find that data for most lakes are consistent with a water source similar to annual runoff, estimated from monthly precipitation and evaporation within the lake basin. Strong evidence for both summer- and winter-biased sources exists, however, with winter bias pervasive in most snow-prone regions. The new analytical framework should improve the rigor of iSW in ecohydrology and related sciences, and our initial results from US lakes suggest that previous interpretations of lakes as unbiased isotope integrators may only be valid in certain climate regimes.

Spatio‐temporal heterogeneity in soil water content is recognized as a common phenomenon, but heterogeneity in the hydrogen and oxygen isotope composition of soil water, which can reveal processes of water cycling within soils, has not been well studied. New advances are being driven by measurement approaches allowing sampling with high density in both space and time. Using in situ soil water vapour probe techniques, combined with conventional soil and plant water vacuum distillation extraction, we monitored the hydrogen and oxygen stable isotopic composition of soil and plant waters at paired sites dominated by grasses and Gambel's oak (Quercus gambelii) within a semiarid montane ecosystem over the course of a growing season. We found that sites spaced only 20 m apart had profoundly different soil water isotopic and volumetric conditions. We document patterns of depth‐ and time‐explicit variation in soil water isotopic conditions at these sites and consider mechanisms for the observed heterogeneity. We found that soil water content and isotopic variability were damped under Q. gambelii, perhaps due in part to hydraulic redistribution of deep soil water or groundwater by Q. gambelii in these soils relative to the grass‐dominated site. We also found some support for H isotope discrimination effects during water uptake by Q. gambelii. In this ecosystem, the soil water content was higher than that at the neighbouring Grass site, and thus, 25% more water was available for transpiration by Q. gambelii compared with the Grass site. This work highlights the role of plants in governing soil water variation and demonstrates that they can also strongly influence the isotope ratios of soil water. The resulting fine‐scale heterogeneity has implications for the use of isotope tracers to study soil hydrology and evaporation and transpiration fluxes to improve understanding of water cycling through the soil–plant–atmosphere continuum.