Aridity and seasonality of precipitation are characteristics of the highland region in Bolivia. Groundwater becomes an important and safe source of water when surficial bodies are intermittent and affected by natural and anthropogenic contamination. Decades of exploitation of the Challapampa aquifer, combined with lack of information required to understand the groundwater circulation, represent a challenge for reservoir management. This study analyzes isotopic compositions of deuterium and oxygen-18 in different stages in the hydrologic cycle to assess flow patterns in the aquifer, especially in the alluvial fan of River Paria, where records are more extensive in space and time. Interpretations are based on existing and new data. Some implications, such as the age of water, the evaporation effect in groundwater and some thermal intrusions are supported by stable isotopes, tritium, radiocarbon, and electrical conductivity records. New results confirm that modern precipitation over the mountains surrounding the study area is the most important origin of water for shallow aquifers until exploited depths, 100 m below surface. The origin of water in deeper depths, 400 m, seems related to infiltration at higher altitudes and longer residence times.

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Resistivity data constitute the largest part of the available information to assess the hydrogeological characteristics of the aquifer system near Oruro, in the central part of the Bolivian Altiplano. Two aquifers are part of this system; top unconsolidated sediments storing fresh water in their granular voids, overlying fractured hard rock formations where saline water was detected in connection to some faults. This study proposes an indirect and cost-effective way to estimate aquifer hydraulic properties for the groundwater management in the region. Hydraulic conductivity and transmissivity in the top aquifer were estimated using an empirical linear relationship between hydraulic conductivity and resistivity. This latter parameter, as well as the aquifer thickness, were obtained from the inverted models corresponding to the geoelectrical tests performed in the study area (electrical resistivity tomography, transient electromagnetic soundings and vertical electrical soundings). The highest estimated transmissivity values are ∼4.0 × 10−2 m2/s located in the centre of the study area, the lowest values are ∼3.4 × 10−3 m2/s, located around thermal intrusions to the south and where the top of the bedrock is shallow (∼20 m depth) to the west. The methodology presented in this study makes wider use of resistivity measurements to identify promising groundwater production sites.