Biogas, a product of anaerobic digestion process that consists mainly of methane and carbon dioxide is a suitable alternative fuel if unwanted impurities are removed as they have a negative impact on the equipment. The most significant technologically troublesome trace compounds that must be removed are siloxanes since they are converted into silica on gas surface engines and turbines resulting in equipment damage. The quality of the gas is certainly improved by reducing the amount of impurities and the end use determines the extent of biogas cleaning needed. The major aim of this study was to compile information that can assist researchers or even designers in selecting a suitable technology to remove siloxanes. Siloxane removal definitely can be achieved using different methods and the effectiveness of each method relies on careful consideration of the characteristics of both biogas and siloxane, as well as the technological aspects of the method. Herein, we review on different cleaning techniques for siloxanes in raw biogas, the negative effects they have, their levels and technologies to reduce their concentrations. This review also incorporates the sources of the siloxanes, the progress to date on their removal and possible ways of regenerating adsorbents. The reviewed literature suggests that biogas upgrading technology should be promoted and encouraged especially in siloxane removal as it has detrimental effects on engines. The parameters and effectiveness of adsorption processes are discussed, and individual adsorbents are compared.
The drawbacks of utilizing nonrenewable energy have quickened innovative work on practical sustainable power sources (photovoltaics) because of their provision of a better-preserved decent environment which is free from natural contamination and commotion. Herein, the synthesis, characterization, and application of Mo chalcogenide nanoparticles (NP) as alternative sources in the absorber layer of QDSSCs is discussed. The successful synthesis of the NP was confirmed as the results from the diffractive peaks obtained from XRD which were positive and agreed in comparison with the standard. The diffractive peaks were shown in the planes (100), (002), (100), and (105) for the MoS2 nanoparticles; (002), (100), (103), and (110) for the MoSe2 nanoparticles; and (0002), (0004), (103), as well as (0006) for the MoTe2 nanoparticles. MoSe2 presented the smallest size of the nanoparticles, followed by MoTe2 and, lastly, by MoS2. These results agreed with the results obtained using SEM analysis. For the optical properties of the nanoparticles, UV–Vis and PL were used. The shift of the peaks from the red shift (600 nm) to the blue shift (270–275 nm and 287–289 nm (UV–Vis)) confirmed that the nanoparticles were quantum-confined. The application of the MoX2 NPs in QDSSCs was performed, with MoSe2 presenting the greatest PCE of 7.86%, followed by MoTe2 (6.93%) and, lastly, by MoS2, with the PCE of 6.05%.
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