Poly (vinylidene fluoride) membranes were prepared by freeze-casting. The effects of PVDF concentration, and freezing temperature on the morphology, crystallization, and performance of prepared membranes were examined. Polymer concentration was varied from 10 to 25 wt%. The freezing temperature was varied from −5 to −25 °C. Dimethyl sulfoxide (DMSO) and distilled water were used as solvents and non-solvents, respectively. The first step of this study was devoted to estimating the optimal concentration of PVDF solution in DMSO. Membranes prepared at different ratios were characterized using physical and mechanical characteristics and porosity. The second step was to optimize the time required for the production of the membranes. In the third step, it was shown that the freezing temperature had a remarkable effect on the morphology of the membranes: as the temperature decreases, there is a transition from spherulite structures to interconnected pores. It was shown that the diversity in the pore pattern for PVDF affects remarkably the water permeability through the polymer membrane. During the monitoring of the spread of crystallized areas during the formation of the membrane, it was found that the crystallization of the solvent begins at localized points of the microscale, further crystallized areas spread radially or unevenly along the surface of the solution, forming contact borders, which can lead to changes in the properties of the membrane in its area.

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