Iron is one of the most common components in water that adversely affect humans, other living organisms and parameters of water bodies. Therefore, during using and consuming natural waters, and discharging sewage into surface water bodies, it is necessary to remove iron compounds from the aquatic environment. The use of capillary materials in water purification processes is a promising area of research. Experimental data proved the high efficiency of capillary materials application, providing higher efficiency of iron ions removal from model solutions for real water sources of different origin compared with the traditional method of settling. The main advantage of the application of materials with capillary properties is the simplicity of implementation of the method and there is no need to use electricity and any additional reagents. The effect of various factors on the process of water deironing with the application of capillary materials was studied. It was found out that the density has a little effect on the process at an iron concentration range from 1 to 5 mg/dm 3 . The increase in competing ions content intensifies the process of divalent ferrous ions transition to trivalent. During the deironing of artesian water, the degree of iron removal exceeded 90 %, while the residual concentration was below the MPC.
Among all known inorganic pollutants of wastewater and natural water that adversely affect water bodies, different living organisms and human beings, iron compounds are the most common. Before discharging the wastewater into water bodies, it is important to remove iron ions from wastewater. The application of capillary materials in water and wastewater treatment is a promising direction of ecology and technology. The capillary properties of materials allow the development of quite simple, autonomous, highly efficient and energy-saving systems for water purification. The aim of the present paper was the investigation of the influence of the basic conditions of the filtration process with the application of capillary materia on the efficiency of iron ions removal. The initial concentration of the model solution, pH and temperature of the filtration process, as well as the contact area of the liquid phase with oxygen of the air were studied. The proposed method is appropriate for the treatment of water in the concentration range from 5 to 10 mg/dm 3 with an optimum pH in the range of 4-7. The experimental data showed high efficiency of capillary materials application, providing sufficient removal of iron ions from low concentrated solutions, compared to the traditional method of precipitation. The main advantage of the capillary materials is the simplicity of their application, quite high degree of purification and there no need to consume electricity or additional reagents, which allows creating autonomous water treatment facilities and plants.
The low degree of mixing is due to the large quantity of components in the of the batch, irregular supply of coal concentrates, fluctuations in their physical and chemical parameters. Research results indicate that increasing the homogeneity of the coal batch through the introduction of organized mixing will improve the physical and mechanical properties of coke. It should be noted that the smallest effect from the use of mixing units is achieved with the batch preparation scheme, which involves grinding all its components in one crushing unit. At the same time, the use one crusher instead two or four makes it possible to achieve a high degree of homogeneity of the batch. In the final grinding schemes, which provide for group or differentiated grinding the components of batch is required to use mixing machines. To ensure the efficiency mixing the components of the coal batch, it is desirable to install mixers in the transfer nodes, on the transfer of the batch from the conveyor to the conveyor or on top of the coal tower, in this case the segregation of the batch is reduced to a minimum. The degree of mixing all indicators of coal batch for 98-99%, which ensure a stabilization of the properties of coke in conditions multi-basin coking raw material base is one of the most important problem of the coal preparation technology for coking Based on the results of the research in terms of coke production of PJSC «ArcelorMittal Kryvyi Rih» found that the large quantity of components in the mixture, the variability of their physicochemical parameters are cause of low degree of mixing the batch. Organized mixing of the coal batch using mixing machines was recommended to implement
Objective: to analyze and determine the potential of alkaline earth bentonite clays of Ukraine for use as a binder in the production of iron ore pellets. Methods: performing rheological studies of bentonite clay samples and their chemical analysis, electron microscopic studies of samples. Results: the analysis of the chemical composition and requirements for the rheological characteristics of bentonite clays used in the production of iron ore pellets at metallurgical enterprises of Russia and Ukraine is carried out. The swelling indicators and water absorption of monoionic forms of bentonites of some deposits in water of different hardness are given. The quality of pellets with bentonites, that have a different exchange complex, during an industrial water of various hardness usage is examined. The analysis of the mineralogical and chemical composition, as well as the size and composition of the exchange complex of alkaline-earth bentonite clays of the Cherkasy deposit (Ukraine), which has the largest reserves of such clays in the CIS is carried out. It is shown that clays suitable for the production of pellets are located near the surface of the earth. A comparative analysis of the strength characteristics of pellets using bentonites with an alkaline and alkaline-earth exchange complex is presented. 484 Comparative tests of pelletizing of charges with different humidity and with the addition of 0.5% alkaline bentonite and a mixture of clays of the IV and II layers of the Cherkasy deposit have been carried out. It is shown that with increasing humidity in granules with both types of binders, the dynamic strength, porosity and temperature of the “impact” of granules increase with a minimum difference in the absolute values of indicators with different binders
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