In this paper, it is shown that specifi c ionic liquids have great potential to be used as additives for tribological applications. The results promise a high load carrying capacity; especially for the cation 3-Octhylthiazolium and long term stability up to temperatures of 120°C is given. However, only extreme pressures/ anti-wear properties are examined in detail with the selected test method. Friction modifi er (FM) effectiveness cannot easily be demonstrated, because of the good performance of the selected base stock. Nevertheless, ionic liquids in general did not change the FM characteristic of the base oil in a negative way. A promising potential for ionic liquids to replace a majority of additives in tribological systems is given. Methods used are Schwing-Reib-Verschleiß test according to DIN ASTM D 5706, and Four Ball Tests according to DIN 51360. Mechanisms related to additives in lubricants are investigated by X-ray photoelectron spectroscopy.
A novel formulation of elastic multi-asperity contacts based on the boundary element method (BEM) is presented for the first time, in which the influence coefficients are numerically calculated using a finite element method (FEM). The main advantage of computing the influence coefficients in this manner is that it makes it also possible to consider an arbitrary load direction and multilayer systems of different mechanical properties in each layer. Furthermore, any form of anisotropy can be modelled too, where Green's functions either become very complicated or are not available at all. The rest of the contact analysis is then performed applying a custom-developed boundary element algorithm. The scheme was tested by considering the frictionless contact between a flat surface and a sphere. The obtained results are in good agreement with the analytical solution known for a Hertzian contact. Applied to either a frictionless or a frictional contact between real surfaces of different samples, our FEM-BEM method has shown that the composite roughness of surfaces in contact uniquely determines the contact pressure distribution.
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