270ChemInform Abstract A first example of partial oxidation of diphosphines leads to heterodifunctional ligands such as (IIIa). This reaction is applicable also for a mixed arsinophosphine and for diphosphines of various alkane chain lengths. In spite of the fact that (IIIa) and (IIIb) appear to exist as conformational isomers, complexes with only one conformation are formed. The title complex (VII) crystallizes in P21/n with Z=4.
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