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Forest fires are one of the main environmental threats in Chile. Fires in this Mediterranean climate region frequently affect native forests and exotic plantations, including in several cases urban and rural settlements. Considering the scarcity of information regarding the fire response dynamics of tree species that are frequently affected by fires, this study aims to establish a flammability classification according to the evolution of the fire initiation risk presented by the most affected forest species in the Valparaíso region. Three exotic species, Eucalyptus globulus, Pinus radiata, and Acacia dealbata, and two native species, Cryptocarya alba and Quillaja saponaria, were studied. Flammability assays indicate that E. globulus, A. dealbata, and C. alba are extremely flammable, whereas P. radiata and Q. saponaria are flammable. Furthermore, E. globulus and A. dealbata have the highest heating values while Q. saponaria has the lowest values. The extreme flammability of E. globulus, A. dealbata, and C. alba indicates a high susceptibility to ignite. Furthermore, the high heat of combustion of E. globulus and A. dealbata can be associated with a high energy release, increasing the risk of fires spreading. In contrast, Q. saponaria has the lowest predisposition to ignite and capacity to release heat. Accordingly, this work shows that all studied tree species contain organic metabolites that are potentially flammable (sesquiterpenes, aliphatic hydrocarbons, alcohol esters, ketones, diterpenes, and triterpenes) and can be considered as drivers of flammability in vegetation. Finally, these preliminary results will aid in the construction of more resilient landscapes in the near future.

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Wildfires in the Valparaíso region (Chile) account for one of the main threats to local biodiversity, ecosystem services and infrastructure. This study focused on producing an initial record of thermo- and physicochemical properties of local forest species. For this purpose, leaf samples of species found in the Peñuelas Lake National Reserve, namely Pinus radiata, Eucalyptus globulus, Acacia dealbata, Quillaja saponaria and Cryptocarya alba, were collected and analysed. Higher and lower heating value, flash point, density and moisture content tests were performed for each sample. Overall results showed that lower heating values measured for both native and exotic species could indicate a high energy release source in wildfires. However, differences in the flash point between species indicated that C. alba and E. globulus had a lower ignition resistance than other species tested, possibly due to a lower flash point. In contrast, Q. saponaria and A. dealbata had the highest flash point for native and exotic species respectively. Finally, all presented data and procedures were aimed at establishing a foundation for a national database of critical forest species properties to be used in wildfire simulation tools. This database will enhance forest fire management effectiveness in Chile.