Parametrically excited surface wave modes on a fluid layer driven by vertical forcing can interact with each other when more than one spatial mode is excited. We have investigated the dynamics of the interaction of two modes that are degenerate in a square layer, but non-degenerate in a rectangular one. Novel experimental techniques were developed for this purpose, including the real-time measurement of all relevant slowly varying mode amplitudes, investigation of the phase-space structure by means of transient studies starting from a variety of initial conditions, and automated determination of stability boundaries as a function of driving amplitude and frequency. These methods allowed both stable and unstable fixed points (sinks, sources, and saddles) to be determined, and the nature of the bifurcation sequences to be clearly established. In most of the dynamical regimes, multiple attractors and repellers (up to 16) were found, including both pure and mixed modes. We found that the symmetry of the fluid cell has dramatic effects on the dynamics. The fully degenerate case (square cell) yields no time-dependent patterns, and is qualitatively understood in terms of third-order amplitude equations whose basic structure follows from symmetry arguments. In a slightly rectangular cell, where the two modes are separated in frequency by a small amount (about 1%), mode competition produces both periodic and chaotic states organized around unstable pure and mixed-state fixed points.

A simple methodology for the determination of the fatty acid composition of edible oils through (1)H NMR is proposed. The method is based on the fact that all fatty acid chains are esterified to a common moiety, glycerol, and the quantification is done directly in the (1)H NMR spectra through the relationship between the areas of a characteristic signal of each fatty acid and a signal of the glycerol moiety, without the use of mathematical equations. The methodology was successfully applied to determine the fatty acid composition of several edible oils, with equivalent results to those given by the AOAC Official method by gas chromatography. Its main advantages are simplicity and the lack of need for sample pre-treatment such as derivatization or extraction.

Os compostos utilizados pelo percevejo da soja Piezodorus guildinii como feromônio de alarme foram caracterizados através da análise da composição química das secreções da glândula metatorácica dos insetos adultos. Além dos hidrocarbonetos característicos, (E)-2-hexenal e (E)-4-oxo-2-hexenal foram detectados como constituintes majoritários. Tais compostos já foram previamente descritos como feromônio de alarme em outras espécies de pentatomídeos.The compounds utilized by the soybean stink bug Piezodorus guildinii as alarm pheromone were characterized by analysis of the chemical composition of the metathoracic scent gland secretions from adult bugs. In addition to characteristic hydrocarbons, (E)-2-hexenal and (E)-4-oxo-2-hexenal were detected as major constituents. These compounds were previously described as alarm pheromone in several other pentatomid species.

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