The phytoalexin resveratrol (3,5,4'-trihydroxystilbene) in edible peanut (Arachis hypogaea L.) and pistachio (Pistacia vera L.) varieties grown in Turkey was analyzed by high-performance liquid chromatographic diode array and gas chromatography-mass spectrometric detection. trans-Resveratrol in six peanut varieties, five pistachio varieties, and four market samples ranged between 0.03 and 1.92 microg/g. The Cerezlik 5025 peanut (1.92 +/- 0.01 microg/g) and Ohadi pistachio genotype (1.67 +/- 0.01 microg/g) had significantly higher trans-resveratrol contents. Peanuts contained 0.03-1.92 microg/g (av = 0.84 microg/g) of trans-resveratrol, whereas pistachio contained 0.09-1.67 microg/g (av = 1.15 microg/g). With exposure to UV light for 1 min, trans-resveratrol concentrations of samples ranged from 0.02 to 1.47 microg/g and those of cis-resveratrol from 0.008 to 0.32 microg/g. The occurrence of resveratrol in peanut and pistachio was confirmed by total ion chromatograms (TIC) of bis[trimethylsilyl]trifluoroacetamide derivatives of resveratrol isomers and comparison of the mass spectral fragmentation data with those of a resveratrol standard. Formation of the cis-isomer in pistachios was higher than in peanuts.
Over the past thirty years, molecular imprinting has aroused great research interest for scientists. This attention can be explained by the serious potential advantages of using molecularly imprinted polymers in place of natural receptors and enzymes such as their superior durability, low-cost and easy preparation. Furthermore molecular imprinting is a promising technique for the preparation of polymer composites with predetermined selectivity and high affinity. This mini review examines and evaluates the preparation technique and utility application of molecularly imprinted polymers (MIPs) in several areas. The review begins with a brief introduction to MIPs with a focus on their preparations and continues with application areas.
Disinfectants are not only cleaning reagents such as soap or detergents but are hygienic materials prepared with the composition of various chemicals. Many classification routes are possible, but they are placed in two main groups, such as organic and inorganic disinfectants. The classification prevails for high level disinfectants and depends on chemical structure. In high-level disinfectants aldehydes, hydrogen peroxide, and chloride type chemicals are used. In contrast, alcohols, phenols, ammonium salts, and iodine solutions are recommended for low disinfectant applications. Soap, iodide, and alcohol solutions are the best antiseptic agents for hand and skin. Iodine-based solutions are good primary tissue and skin disinfectants. The alcohol solutions have a good inhibitory effect on many microorganisms, micro bacteria, fungi, and various viruses. These solution types are not hazardous to use as both antiseptic and surface disinfectants compared to many other chemicals.
Nitrogen compounds being important for the vital activities of living things are produced by the nitrification process and occurred spontaneously in the nitrogen cycle. Human vital activities are also responsible for the extra nitrogen released into the atmosphere. So, both human and environmental healths are negatively affected by the increasing nitrate and nitrate amounts in water and soil. For this reason, it is aimed to ensure regular control of nitrates and nitrites at certain levels in order to protect the universe and all living things. Their precise and selective determination by various methods is very important. Their determinations can usually be made by using electrochemical, spectrophotometric, chromatographic and titrimetric methods. Nowadays instead of these techniques, sensors are preferred in determining nitrate and nitrite due to their easy, fast, selective and sensitive application properties. Furthermore, polymeric materials have shown great promise for different sensing applications such as gas, humidity, explosive and water pollutants. Sensors, which are developed by polymerization, have very high quality for the determination of nitrite. The highly sensitive results of optical and electrochemical sensors attract the attention of researchers. In this review, different detection methods for nitrite ions and various studies on the preparation of polymeric sensors that can selectively capture the nitrite ions in complex matrices are examined.
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