No abstract

Ionic conductors are normally prepared from water-based materials in the solid form and feature a combination of intrinsic transparency and stretchability. The sensitivity toward humidity inevitably leads to dehydration or deliquescence issues, which will limit the long-term use of ionic conductors. Here, a novel ionic conductor based on natural bacterial cellulose (BC) and polymerizable deep eutectic solvents (PDESs) is developed for addressing the abovementioned drawbacks. The superstrong three-dimensional nanofiber network and strong interfacial interaction endow the BC−PDES ionic conductor with significantly enhanced mechanical properties (tensile strength of 8 × 10 5 Pa and compressive strength of 6.68 × 10 6 Pa). Furthermore, compared to deliquescent PDESs, BC−PDES composites showed obvious mechanical stability, which maintain good mechanical properties even when exposed to high humidity for 120 days. These materials were demonstrated to possess multiple sensitivity to external stimulus, such as strain, pressure, bend, and temperature. Thus, they can easily serve as supersensitive sensors to recognize physical activity of humans such as limb movements, throat vibrations, and handwriting. Moreover, the BC−PDES ionic conductors can be used in flexible, patterned electroluminescent devices. This work provides an efficient strategy for making cellulose-based sustainable and functional ionic conductors which have broad application in artificial flexible electronics and other products.

Lignosulfonate, a waste by-product from the paper industry, was simply assembled with HfCl4 to construct sustainable catalysts (Hf–LigS) for highly efficient reductive upgrading of 5-hydroxymethylfurfural.

Carboxymethyl cellulose-derived Co nanocatalysts sheathed in N-doped graphene exhibited an excellent catalytic activity for base-free transfer hydrodeoxygenation of vanillin with formic acid.