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To determine the effect of in vitro gastrointestinal digestion on the release and antioxidant capacity of encapsulated and nonencapsulated phenolics carob pulp extracts, unripe and ripe carob pulp extracts were microencapsulated with polycaprolactone via double emulsion/solvent evaporation technique. Microcapsules' characterization was performed using scanning electron microscopy and Fourier transform infrared spectrometry analysis. Total phenolics and flavonoids content and antioxidant activities (ORAC, DPPH, and FRAP) were evaluated after each digestion step. The release of phenolic acids and flavonoids was measured along the digestion process by HPLC-MS/MS analysis. The most important phenolics and flavonoids content as well as antioxidant activities were observed after gastric and intestinal phases for nonencapsulated and encapsulated extracts, respectively. The microencapsulation of carob polyphenols showed a protective effect against pH changes and enzymatic activities along digestion, thereby promoting a controlled release and targeted delivery of the encapsulated compound, which contributed to an increase in its bioaccessibility in the gut.

Poly (lactic acid) (PLA) was melt blended in a twin screw extruder using an ethylene-methyl acrylate-glycidyl methacrylate rubber as a toughener. PLA/rubber blends were immiscible as observed by scanning electron microscopy. Impact strength and ductility of PLA were improved by the addition of the rubber at the expense of strength and stiffness. An organo-montmorillonite (OMMT) was used at 2 wt % to counteract the negative effect of the rubber on modulus, and balanced properties were observed at 10 wt % rubber content. X-ray diffraction and transmission electron microscopy revealed the formation of intercalated/exfoliated structure in the ternary nanocomposites. Thermal behavior analysis indicated that the degree of crystallinity is slightly affected by the clay and the rubber. Both the clay and the rubber decreased the crystallization temperature of PLA and acted as nucleating agents for PLA. The viscosity of the mixtures as measured by melt flow index was highly influenced by the rubber and the OMMT.

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