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properties. In the cases of Au-SiO x nanoflowers and Au-silica (SiO 2 ) core-shell structures, that coupling effect leads to an enhancement of the PL emission of the systems. [3] Additionally, Au-SiO 2 coreshell nanoparticles show a wide tunability of LSPR as a function of the thickness of the SiO 2 nanoshell. [4] Therefore, the tailored design of the shape and composition of Au-SiO x nanostructures is crucial for their functional properties, and the development of an easy-to-control way is indispensable for the final applications.Au-SiO x nanostructures are usually synthesized in chemical solutions, which not only makes the final products difficult to control, but also harms the environment. [3b,4] On the contrary, physical routes provide well-controlled and environmental friendly methods to synthetize Au-SiO x nanostructures. [3a,5]

The morphology evolution by thermal annealing induced dewetting of gold (Au) thin films on silicon (Si) substrates with a native oxide layer and its dependences on annealing temperature and atmosphere are investigated. Both dewetting degree of thin film and Au/Si interdiffusion extent are enhanced with the annealing temperature. Au/Si interdiffusion can be observed beyond 800 °C and Au–Si droplets form in both argon and oxygen (Ar + O2) and argon and hydrogen (Ar + H2) environments. In Ar + O2 case, the passive oxidation (Si + O2 → SiO2) of diffused Si happens and thick silicon oxide (SiOx) covering layers are formed. A high temperature of 1050 °C can even activate the outward growth of free-standing SiOx nanowires from droplets. Similarly, annealing at 800 °C under Ar + H2 situation also enables the slight Si passive oxidation, resulting in the formation of stripe-like SiOx areas. However, higher temperatures of 950–1050 °C in Ar + H2 environment initiate both the SiOx decomposition and the Si active oxidation (2Si + O2 → 2SiO(g)), and the formation of solid SiOx is absent, leading to the only formation of isolated Au–Si droplets at elevated temperatures and droplets evolve to particles presenting two contrasts due to the Au/Si phase separation upon cooling.

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