A hybrid biopolymer/electronic polymer electrode is demonstrated here to extract metal ions, in this case lead, from water. The hybrid material consists of poly(3,4‐ethylenedioxythiophene)/polystyrene sulfonate (PEDOT/PSS) and the biopolymer lignin (LG) and is prepared by a simple one‐step galvanostatic polymerization from aqueous solution. The hybrid material is characterized by cyclic voltammetry, electrochemical quartz microbalance, X‐ray photoelectron spectroscopy, and scanning electron microscopy techniques. The electrochemical and spectroscopic results confirm that lead ions can be adsorbed on the composites films from a neutral solution of lead ions by applying a negative potential and subsequently desorbed from the hybrid films by applying positive potential. The adsorption capacity for lead ions on PEDOT/PSS is 245.5 mg g−1 and is almost doubled to 452.8 mg g−1 by incorporating LG into PEDOT/PSS.